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08953

Supelco

1-Bromobutane

analytical standard

Sinônimo(s):

Butyl bromide

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About This Item

Fórmula linear:
CH3(CH2)3Br
Número CAS:
109-65-9
Peso molecular:
137.02
Beilstein:
1098260
Número CE:
203-691-9
Número MDL:
MFCD00000260
Código UNSPSC:
41116107
ID de substância PubChem:
329748647
NACRES:
NA.24
Preço e disponibilidade não estão disponíveis no momento.

grau

analytical standard

Nível de qualidade

100

densidade de vapor

4.7 (vs air)

pressão de vapor

150 mmHg ( 50 °C)
40 mmHg ( 25 °C)

Ensaio

≥99.5% (GC)

temperatura de autoignição

509 °F

prazo de validade

limited shelf life, expiry date on the label

Lim. expl.

2.8-6.6 %, 100 °F

técnica(s)

HPLC: suitable
gas chromatography (GC): suitable

índice de refração

n20/D 1.439 (lit.)
n20/D 1.440

p.e.

100-104 °C (lit.)

pf

−112 °C (lit.)

densidade

1.276 g/mL at 25 °C (lit.)

aplicação(ões)

environmental

Formato

neat

cadeia de caracteres SMILES

CCCCBr

InChI

1S/C4H9Br/c1-2-3-4-5/h2-4H2,1H3

chave InChI

MPPPKRYCTPRNTB-UHFFFAOYSA-N

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Descrição geral

1-Bromobutane, an organobromine compound, is a commonly used industrial solvent for cleaning, extraction and chemical synthesis.[1]

Aplicação

1-Bromobutane may be used as a derivatization reagent for multiple functional groups (amino, carboxyl, and phenolic hydroxyl groups) of amino acids to improve hydrophobicities and basicities of the amino acids.[2] It may also be used as an internal standard for the quantification of 1- and 2-bromopropane in human urine by headspace gas chromatography.[3]

Palavra indicadora

Danger

Classificações de perigo

Aquatic Chronic 2 - Carc. 2 - Flam. Liq. 2 - Repr. 1B - Skin Irrit. 2 - STOT RE 2 Inhalation - STOT SE 3

Órgãos-alvo

Liver, Respiratory system

Código de classe de armazenamento

3 - Flammable liquids

Classe de risco de água (WGK)

WGK 2

Ponto de fulgor (°F)

50.0 °F - closed cup

Ponto de fulgor (°C)

10 °C - closed cup

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificados de análise (COA)

Lot/Batch Number
BCCL7366
BCCK5613
BCCF7439
BCCD4011
BCBW7313

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Development of a headspace gas chromatographic test for the quantification of 1-and 2-bromopropane in human urine
B?Hymer C and Cheever KL
Journal of Chromatography. B, Biomedical Sciences and Applications, 814(1), 185-189 (2005)
W C E Schofield et al.
ACS applied materials & interfaces, 1(12), 2763-2767 (2010-04-02)
Existing methods for imparting antibacterial performance to solid surfaces tend to either be substrate-specific or rely upon leaching modes of action that cause ecological damage. An alternative approach is outlined comprising plasmachemical functionalization of solid surfaces with poly(4-vinyl pyridine) moieties
Sang Kyu Lee et al.
Food and chemical toxicology : an international journal published for the British Industrial Biological Research Association, 48(10), 2707-2711 (2010-07-06)
Halogenated organic compounds, such as 1-bromobutane (1-BB), have been used as cleaning agents, agents for chemical syntheses, or extraction solvents. In the present study, hepatotoxic effects of 1-BB and its conjugation with glutathione (GSH) were investigated in female BALB/c mice.
Congbo Cai et al.
Journal of magnetic resonance (San Diego, Calif. : 1997), 211(2), 162-169 (2011-06-15)
Recently, a method based on intermolecular multiple quantum coherences (iMQCs) has been proposed to obtain high-resolution 2D COSY spectra in inhomogeneous fields via 3D acquisitions. However, the very long acquisition time prevents its practical application. To overcome this shortage, the
Christina Lederle et al.
The Journal of chemical physics, 134(6), 064512-064512 (2011-02-17)
Mixtures of the monohydroxy alcohol n-butanol with n-bromobutane are investigated via dielectric and nuclear magnetic resonance (NMR) techniques. Static- and pulsed-field gradient proton NMR yielded self-diffusion coefficients as a function of concentration and temperature. To monitor reorientational motions, broadband dielectric
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