900421

9-Mesityl-3,6-di-tert-butyl-10-phenylacridinium tetrafluoroborate

≥95%

• Sinônimo(s): 3,6-Bis(1,1-dimethylethyl)-10-phenyl-9-(2,4,6-trimethylphenyl)-acridinium tetrafluoroborate, 3,6-Di-tert-butyl-9-(2,4,6-trimethylphenyl)-10-phenylacridinium tetrafluoroborate
• Fórmula empírica (Notação de Hill): C₃₆H₄₀BF₄N
• Número CAS: 1810004-87-5
• Peso molecular: 573.51
• Número MDL: MFCD31381908
• Código UNSPSC: 12352005
• NACRES: NA.22

Propriedades

• Nível de qualidade: 100
• Ensaio: ≥95%
• Formulário: powder or crystals
• adequação da reação: core: acridinium; reagent type: catalyst; reaction type: Photocatalysis
• pf: 277.2 °C
• ativação do fotocatalisador: 455 nm
• cadeia de caracteres SMILES: [F-][B+3]([F-])([F-])[F-].C=1C=CC(=CC1)[N+]=2C=3C=C(C=CC3C(=C4C=CC(=CC42)C(C)(C)C)C=5C(=CC(=CC5C)C)C)C(C)(C)C
• InChI: InChI=1S/C36H40N.BF4/c1-23-19-24(2)33(25(3)20-23)34-29-17-15-26(35(4,5)6)21-31(29)37(28-13-11-10-12-14-28)32-22-27(36(7,8)9)16-18-30(32)34;2-1(3,4)5/h10-22H,1-9H3;/q+1;-1
• chave InChI: YUNSHKYOOCWQRB-UHFFFAOYSA-N

Descrição

Aplicação

9-Mesityl-3,6-di-tert-butyl-10-phenylacridinium tetrafluoroborate is an acridium-based photocatalyst that can be an alternative to transition-metal-based photocatalysts due to its higher chemical stability and attenuated redox potential.

When employed with TEMPO, this acridinium photocatalyst promotes the site-selective amination of a variety of simple and complex aromatics with heteroaromatic azoles. When ammonium carbamate is used as the amine, anilines can be achieved directly.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Outras notas

Site-selective arene C-H amination via photoredox catalysis

Informações de segurança

• Código de classe de armazenamento: 11 - Combustible Solids
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): Not applicable
• Ponto de fulgor (°C): Not applicable