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272345

Sigma-Aldrich

2,4,6-Triphenylpyrylium tetrafluoroborate

98%

Sinônimo(s):

2,4,6-Triphenylpyrylium fluoborate (6CI), 2,4,6-Triphenylpyrylium fluoroborate, 2,4,6-Triphenylpyrylium tetrafluoroborate (7CI), TPPT

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About This Item

Fórmula empírica (Notação de Hill):
C23H17BF4O
Número CAS:
448-61-3
Peso molecular:
396.19
Beilstein:
3586533
Número CE:
207-186-4
Número MDL:
MFCD00012001
Código UNSPSC:
12352100
ID de substância PubChem:
24856467
NACRES:
NA.22

Ensaio

98%

forma

powder

adequação da reação

reaction type: Photocatalysis
reagent type: catalyst

pf

250-251 °C (lit.)

ativação do fotocatalisador

462 nm

cadeia de caracteres SMILES

F[B-](F)(F)F.c1ccc(cc1)-c2cc([o+]c(c2)-c3ccccc3)-c4ccccc4

InChI

1S/C23H17O.BF4/c1-4-10-18(11-5-1)21-16-22(19-12-6-2-7-13-19)24-23(17-21)20-14-8-3-9-15-20;2-1(3,4)5/h1-17H;/q+1;-1

chave InChI

VQYPWMWEJGDSTF-UHFFFAOYSA-N

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Aplicação

2,4,6-Triphenylpyrylium tetrafluoroborate was used as a sensitizer to carry out the photooxidation of cathecol. It was also used in the preparation of three N-alkylpyridinium photosensitizers by reacting with (1R,2S)-(-)-norephedrine, (S)-(+)-2-(aminomethyl)pyrrolidine and (R)-(-)-1-cyclohexylethylamine.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Código de classe de armazenamento

11 - Combustible Solids

Classe de risco de água (WGK)

WGK 3

Equipamento de proteção individual

dust mask type N95 (US), Eyeshields, Gloves

Certificados de análise (COA)

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[Experiences with replacement of the eyelid-levator].
K Hollmann
Fortschritte der Kiefer- und Gesichts-Chirurgie, 22, 98-99 (1977-01-01)
Mercedes Alvaro et al.
The Journal of organic chemistry, 67(15), 5184-5189 (2002-07-20)
Three N-alkylpyridinium photosensitizers having chiral alkyl groups have been prepared by reacting 2,4,6-triphenylpyrylium tetrafluoroborate ion with (1R,2S)-(-)-norephedrine, (S)-(+)-2-(aminomethyl)pyrrolidine, and (R)-(-)-1-cyclohexylethylamine. Laser flash photolysis allows detection of the corresponding triplet excited states that are quenched by hydrogen atom donors and electron
Remigiusz Bąchor et al.
International journal of molecular sciences, 21(9) (2020-05-07)
Detection of podocytes in urine might serve as a useful diagnostic tool in both primary and secondary glomerular diseases. The utility of podocyturia has been confirmed for both pre-eclampsia and glomerulonephritis. Here, we present a new and sensitive method for
Żaneta Rembisz et al.
Journal of chromatography. A, 1407, 184-192 (2015-07-15)
A high-performance liquid chromatography method based on pre-column derivatization with the pyrylium salts (4-[p-(N,N-dimethylamino)phenyl]-2,6-diphenylpyrylium perchlorate (LN1) and 2,4,6-triphenylpyrylium tetrafluoroborate (L1)) has been developed for the determination of sulfide. After the reaction of sulfide ions with LN1 or L1 aiming at

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