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Sigma-Aldrich

2-Morpholinoethyl isocyanide

≥98.0% (GC)

Sinônimo(s):

4-(2-Isocyanoethyl)morpholine, MEI

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About This Item

Fórmula empírica (Notação de Hill):
C7H12N2O
Número CAS:
78375-48-1
Peso molecular:
140.18
Beilstein:
4666990
Número MDL:
MFCD00040506
Código UNSPSC:
12352100
ID de substância PubChem:
57652222
NACRES:
NA.22

Nível de qualidade

200

Ensaio

≥98.0% (GC)

forma

liquid

índice de refração

n20/D 1.469

pb

72-73 °C/0.7 mmHg (lit.)

densidade

1.017 g/mL at 20 °C (lit.)

temperatura de armazenamento

−20°C

cadeia de caracteres SMILES

[C-]#[N+]CCN1CCOCC1

InChI

1S/C7H12N2O/c1-8-2-3-9-4-6-10-7-5-9/h2-7H2

chave InChI

MFRZPLYKVDHOSN-UHFFFAOYSA-N

Categorias relacionadas

Aplicação

2-Morpholinoethyl isocyanide can be used for the synthesis of:
  • Nitrogen acyclic carbene (NAC) complexes to be used as catalysts for the synthesis of phenol and hydration of alkynes.
  • Variety of imidazo[1,2-a]pyridines and α-acylaminoamides by Ugi condensation reaction.
  • 2-Aminobenzoxazoles and 3-aminobenzoxazines having important therapeutic activities.

It can also be used as a ligand in bis-cyclometalated iridium complexes for the organic light emitting diodes (OLEDs).

Outras notas

Potent coupling reagent for peptide synthesis giving higher yields and less racemization than DCCI; Reagent used in a Passerini-like reaction to alpha-hydroxy amides

Pictogramas

Skull and crossbones
GHS06

Palavra indicadora

Danger

Classificações de perigo

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Órgãos-alvo

Respiratory system

Código de classe de armazenamento

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

230.0 °F - closed cup

Ponto de fulgor (°C)

110 °C - closed cup

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Certificados de análise (COA)

Busque Certificados de análise (COA) digitando o Número do Lote do produto. Os números de lote e remessa podem ser encontrados no rótulo de um produto após a palavra “Lot” ou “Batch”.

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