520160

Shi Epoxidation Diketal Catalyst

98%

• Sinônimo(s): 1,2:4,5-Di-O-isopropylidene-β-D-erythro-2,3-hexodiulo-2,6-pyranose
• Fórmula empírica (Notação de Hill): C₁₂H₁₈O₆
• Número CAS: 18422-53-2
• Peso molecular: 258.27
• Número MDL: MFCD11865369
• Código UNSPSC: 12352005
• ID de substância PubChem: 24874093
• NACRES: NA.22

Propriedades

• Ensaio: 98%
• atividade óptica: [α]20/D −120.9°, c = 1 in chloroform
• características do produto alternativo mais ecológico: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• pf: 102-104 °C (lit.)
• categoria alternativa mais ecológica: , Aligned
• cadeia de caracteres SMILES: CC1(C)O[C@@H]2CO[C@]3(COC(C)(C)O3)C(=O)[C@@H]2O1
• InChI: 1S/C12H18O6/c1-10(2)15-6-12(18-10)9(13)8-7(5-14-12)16-11(3,4)17-8/h7-8H,5-6H2,1-4H3/t7-,8-,12+/m1/s1
• chave InChI: IVWWFWFVSWOTLP-RWYTXXIDSA-N

Descrição

Descrição geral

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Aplicação

Highly selective and active organocatalyst for the asymmetric epoxidation of alkenes with hydrogen peroxide. Green epoxidation catalyst of choice according to Glaxo-Smith-Kline's reagent guide.

An Efficient Catalytic Asymmetric Epoxidation Method

Use of an Iridium-Catalyzed Redox-Neutral Alcohol-Amine Coupling on Kilogram Scale for the Synthesis of a GlyT1 Inhibitor

This organocatalyst is able to epoxidize trans alkenes and certain cis alkenes with good to excellent yields and selectivities.

Informações de segurança

• Código de classe de armazenamento: 11 - Combustible Solids
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): Not applicable
• Ponto de fulgor (°C): Not applicable
• Equipamento de proteção individual: Eyeshields, Gloves, type N95 (US)