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Sigma-Aldrich

Palladium(II) chloride solution

5 wt. % in 10 wt. % HCl

Sinônimo(s):

Dichloropalladium, Palladium dichloride, Palladous chloride

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50 ML
R$ 2.898,00

R$ 2.898,00


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50 ML
R$ 2.898,00

About This Item

Fórmula linear:
PdCl2
Número CAS:
Peso molecular:
177.33
Número MDL:
Código UNSPSC:
12161600
ID de substância PubChem:
NACRES:
NA.22

R$ 2.898,00


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Formulário

liquid

Nível de qualidade

adequação da reação

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

concentração

5 wt. % in 10 wt. % HCl

densidade

1.06 g/mL at 25 °C

cadeia de caracteres SMILES

Cl[Pd]Cl

InChI

1S/2ClH.Pd/h2*1H;/q;;+2/p-2

chave InChI

PIBWKRNGBLPSSY-UHFFFAOYSA-L

Descrição geral

Palladium(II) chloride is a representative salt of Pd(II) that is used as a precursor to prepare palladium catalysts for various reactions, such as Heck coupling, Suzuki coupling, Sonagashira coupling, and Buchwald-Hartwig coupling. It is also used as an oxidizing agent.

Aplicação

Used in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar.[1]

Palavra indicadora

Danger

Frases de perigo

Classificações de perigo

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Skin Sens. 1

Código de classe de armazenamento

8B - Non-combustible corrosive hazardous materials

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable


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Mathis, M. et al.
Chemistry of Materials, 10, 3568-3568 (1998)
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Chemistry (Weinheim an der Bergstrasse, Germany), 18(18), 5612-5619 (2012-03-31)
First-principles molecular dynamics coupled with metadynamics have been used to gain a deeper insight into the reaction mechanism of the Wacker process by determining the nature of the active species. An explicit and dynamic representation of the aqueous solvent, which
Maria Elisabete Machado et al.
Journal of chromatography. A, 1274, 165-172 (2013-01-10)
The separation of the organic sulfur compounds (OSC) of petroleum or its heavy fractions is a critical step and is essential for the correct characterization of these compounds, especially due to similar physical and chemical properties of polycyclic aromatic sulfur
[(RCN)2PdCl2]-catalyzed E/Z isomerization of alkenes: a non-hydride binuclear addition-elimination pathway.
Emily H P Tan et al.
Angewandte Chemie (International ed. in English), 50(41), 9602-9606 (2011-09-23)
Feng-Quan Yuan et al.
Chemical communications (Cambridge, England), 47(18), 5289-5291 (2011-04-01)
We present a PdCl(2)-catalyzed protocol for highly efficient allylation and benzylation of a rich variety of N-, O-, and S-containing heteroarenes under base/acid, additive, and ligand-free conditions. The method represents the very few examples for simple, universally applicable, clean, and

Questions

  1. Does the 5 wt. % in 10 wt. % HCl mean PdCl2 weight percent or just the Pd weight percent? i.e if the solution weight is 100g, is the mass of Pd 5g or mass of PdCl2 5g?

    1 answer
    1. 5 wt% is the weight of PdCl2. If the solution weight is 100g, the mass of PdCl2 is 5g.

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