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Sigma-Aldrich

Benzylmagnesium chloride solution

2.0 M in THF

Sinônimo(s):

(Phenylmethyl)magnesium chloride, Benzylchloromagnesium, Chloro(phenylmethyl)magnesium

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100 ML
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Disponível para enviar em07 de abril de 2025Detalhes


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100 ML
R$ 1.116,00
800 ML
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About This Item

Fórmula linear:
C6H5CH2MgCl
Número CAS:
Peso molecular:
150.89
Beilstein:
878506
Número MDL:
Código UNSPSC:
12352103
ID de substância PubChem:
NACRES:
NA.22

R$ 1.116,00


Disponível para enviar em07 de abril de 2025Detalhes


Solicite uma grande encomenda

Nível de qualidade

adequação da reação

reaction type: Grignard Reaction

concentração

2.0 M in THF

densidade

1.031 g/mL at 25 °C

grupo funcional

phenyl

cadeia de caracteres SMILES

Cl[Mg]Cc1ccccc1

InChI

1S/C7H7.ClH.Mg/c1-7-5-3-2-4-6-7;;/h2-6H,1H2;1H;/q;;+1/p-1

chave InChI

NRAFPLGJPPJUNB-UHFFFAOYSA-M

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Descrição geral

Benzylmagnesium chloride is an organometallic compound that acts as a Lewis acid and a strong base.[1]

Aplicação

Benzylmagnesium chloride (Grignard reagent) can be used as an alkylating reagent:
  • For alkylating quinolyl-functionalized Cp−chromium(III) complexes which are used as precursors for the preparation of active olefin polymerization catalysts.[2]
  • In the synthesis of 2,3-disubstituted benzopyran-4-ones[3], 6-chloro-8-methylpurine derivative[4], and phenylalanine derivatives.[5]

Palavra indicadora

Danger

Frases de perigo

Classificações de perigo

Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

Órgãos-alvo

Central nervous system, Respiratory system

Perigos de suplementos

Código de classe de armazenamento

3 - Flammable liquids

Classe de risco de água (WGK)

WGK 2

Ponto de fulgor (°F)

1.4 °F - closed cup

Ponto de fulgor (°C)

-17 °C - closed cup

Equipamento de proteção individual

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Certificados de análise (COA)

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Encontre a documentação dos produtos que você adquiriu recentemente na biblioteca de documentos.

Visite a Biblioteca de Documentos

Dichotomy in regioselective cross-coupling reactions of 6, 8-dichloropurines with phenylboronic acid and methylmagnesium chloride: synthesis of 6, 8-disubstituted purines
Hocek M, et al.
Synthesis, 2004(06), 889-894 (2004)
A facile three-step synthesis of 1, 2-amino alcohols using the Ellman homochiral tert-butylsulfinamide
Barrow JC, et al.
Tetrahedron Letters, 42(11), 2051-2054 (2001)
A novel synthesis of 2, 3-disubstituted benzopyran-4-ones and application to the solid phase
Harikrishnan LS and Showalter HD H
Tetrahedron, 56(4), 515-519 (2000)
Benzylmagnesium Chloride
Herman G
eEROS (Encyclopedia of Reagents for Organic Synthesis) (2001)
Quinolyl-functionalised Cp-chromium polymerisation catalysts: synthesis and crystal structures of alkylation products
Enders M, et al.
Journal of Organometallic Chemistry, 687(1), 125-130 (2003)

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

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