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Transfer of eight phthalates through the milk chain--a case study.

Environment international (2012-11-10)
T Fierens, M Van Holderbeke, H Willems, S De Henauw, I Sioen
ZUSAMMENFASSUNG

This survey determined the levels of eight phthalates - i.e. dimethyl phthalate (DMP), diethyl phthalate (DEP), diisobutyl phthalate (DiBP), di-n-butyl phthalate (DnBP), benzylbutyl phthalate (BzBP), di(2-ethylhexyl) phthalate (DEHP), dicyclohexyl phthalate (DCHP) and di-n-octyl phthalate (DnOP) - in several Belgian milk and dairy products. Samples were obtained from various farms, a dairy factory and from different shops in order to investigate phthalate contamination "from farm to fork". At several stages in the milk chain, product contamination with phthalates - mostly DiBP, DnBP, BzBP and DEHP - was observed. At farm level, the mechanical milking process and the intake of phthalate containing feed by the cattle were found to be possible contamination sources. At industry and retail level, contact materials including packaging materials were additional contamination sources for phthalates in milk and dairy products.

MATERIALIEN
Produktnummer
Marke
Produktbeschreibung

Sigma-Aldrich
Phthalsäuredibutylester, 99%
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Phthalsäure-bis-2-ethylhexylester, ≥99.5%
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Diethylphthalat, 99.5%
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Dimethylphthalat, ≥99%
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Dicyclohexylphthalat, 99%
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Diisobutylphthalat, 99%
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Kaliumhydrogenphthalat, BioXtra, ≥99.95%
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Diethylphthalat, ≥99%
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Phthalsäure-di-n-octylester, ≥98.0% (GC)
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Phthalsäure, ACS reagent, ≥99.5%
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Dimethylphthalat, ≥99%
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Kaliumphthalat, einbasisch, BioUltra, ≥99.5% (T)
Supelco
Di-(2-ethylhexyl)-phthalat -Lösung, certified reference material, 2000 μg/mL in methanol
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Kaliumphthalat, einbasisch, ACS reagent, acidimetric standard
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Kaliumphthalat, einbasisch, puriss. p.a., ≥99.5% (T)
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Phthalsäure-bis-2-ethylhexylester, PESTANAL®, analytical standard
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Di-n-butylphthalat -Lösung, certified reference material, 5000 μg/mL in methanol
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Kaliumphthalat, einbasisch, reference material for titrimetry, certified by BAM, >99.5%
Sigma-Aldrich
Phthalsäure Dikaliumsalz, 98%
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Phthalsäure, puriss. p.a., ≥99.5% (T)
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Phthalsäure-bis-2-ethylhexylester, Selectophore
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Phthalsäuredibutylester, PESTANAL®, analytical standard
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Phthalsäure, reagent grade, 98%
Supelco
Dimethylphthalat, PESTANAL®, analytical standard
Supelco
Phthalsäure-bis-2-ethylhexylester, certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
Supelco
Phthalsäure-di-n-octylester, analytical standard
Supelco
Kaliumphthalat, einbasisch, Standard for quantitative NMR, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
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Diisobutylphthalat, certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
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Phthalsäuredibutylester, certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
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Diethylphthalat, PESTANAL®, analytical standard