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Merck

179922

Sigma-Aldrich

Kaliumphthalat, einbasisch

ACS reagent, acidimetric standard

Synonym(e):

KHP, Kaliumbiphthalat, Kaliumhydrogenphthalat, Phthalsäure Kaliumsalz

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€ 31,90
500 G
€ 102,00
1 KG
€ 153,00

€ 31,90


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100 G
€ 31,90
500 G
€ 102,00
1 KG
€ 153,00

About This Item

Lineare Formel:
HOOCC6H4COOK
CAS-Nummer:
Molekulargewicht:
204.22
Beilstein:
3637128
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352100
PubChem Substanz-ID:
NACRES:
NA.21

€ 31,90


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Qualität

ACS reagent
acidimetric standard

Qualitätsniveau

Assay

99.95-100.05% dry basis

Form

crystals

Verunreinigungen

≤0.002% S compounds
≤0.003% Cl compounds
≤0.005% insolubles

pH-Wert

4.00-4.02 (25.0 °C±0.2 °C, 0.05 M)

mp (Schmelzpunkt)

295-300 °C (dec.) (lit.)

Kationenspuren

Fe: ≤5 ppm
Na: ≤0.005%
heavy metals: ≤5 ppm (by ICP)

Funktionelle Gruppe

carboxylic acid

SMILES String

[K+].OC(=O)c1ccccc1C([O-])=O

InChI

1S/C8H6O4.K/c9-7(10)5-3-1-2-4-6(5)8(11)12;/h1-4H,(H,9,10)(H,11,12);/q;+1/p-1

InChIKey

IWZKICVEHNUQTL-UHFFFAOYSA-M

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Anwendung

Potassium phthalate monobasic may be used as a primary standard in acidimetric titration[1] and also to prepare potassium phthalate buffer solution for pH calibration.[2][3]

Lagerklassenschlüssel

13 - Non Combustible Solids

WGK

WGK 1

Flammpunkt (°F)

387.1 °F - Pensky-Martens closed cup

Flammpunkt (°C)

197.3 °C - Pensky-Martens closed cup

Persönliche Schutzausrüstung

Eyeshields, Gloves, type N95 (US)


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Determination of standard pH values for potassium hydrogen phthalate reference buffer solutions in 10, 20, 50, 64 and 84.2 wt per cent methanol/water mixed solvents at temperatures from 283.15 to 313.15 K.
Mussini T, et al.
Electrochimica Acta, 28(11), 1593-1598 (1983)
2, 4, 6-Trinitrobenzoic acid as a primary standerd in acidimetry.
Smith GF and Wilkins DH.
Analytica Chimica Acta, 8, 209-216 (1953)
J M Padró et al.
Talanta, 107, 95-102 (2013-04-20)
Dispersive ionic liquid-liquid microextraction combined with liquid chromatography and UV detection was used for the determination of two antichagasic drugs in human plasma: nifurtimox and benznidazole. The effects of experimental parameters on extraction efficiency-the type and volume of ionic liquid
Martha M Téllez-Rojo et al.
The Science of the total environment, 461-462, 386-390 (2013-06-12)
Previous studies suggest that prenatal phthalate exposure affects neurodevelopment and behavior during the first years of life. To evaluate the effect of maternal urinary concentrations of phthalate metabolites during pregnancy on mental and psychomotor development in children 24-36 months of
Randi J Bertelsen et al.
Environmental health perspectives, 121(2), 251-256 (2012-11-21)
High-molecular-weight phthalates in indoor dust have been associated with asthma in children, but few studies have evaluated phthalate biomarkers in association with respiratory outcomes. We explored the association between urinary concentrations of phthalate metabolites and current asthma. In a cross-sectional

Questions

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    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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