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241431

Sigma-Aldrich

Wolframhexacarbonyl

97%

Synonym(e):

Hexacarbonyltungsten, Tungsten carbonyl

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About This Item

Lineare Formel:
W(CO)6
CAS-Nummer:
14040-11-0
Molekulargewicht:
351.90
EG-Nummer:
237-880-2
MDL-Nummer:
MFCD00011462
UNSPSC-Code:
12352103
PubChem Substanz-ID:
24854483
NACRES:
NA.23
Preise und Verfügbarkeit sind derzeit nicht verfügbar.

Dampfdichte

12.1 (vs air)

Qualitätsniveau

100

Dampfdruck

1.2 mmHg ( 67 °C)

Assay

97%

Form

solid

Eignung der Reaktion

core: tungsten
reagent type: catalyst

Verunreinigungen

<1% Mo

mp (Schmelzpunkt)

150 °C (lit.)

Dichte

2.65 g/mL at 25 °C (lit.)

SMILES String

[W].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

InChI

1S/6CO.W/c6*1-2;

InChIKey

FQNHWXHRAUXLFU-UHFFFAOYSA-N

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Verwandte Kategorien

Anwendung

Precursor to a Fischer carbene complex which reduces Pd(II) to nanoparticulate Pd(0) that is catalytically active in Hiyama cross-coupling.[1]
Tungsten hexacarbonyl, [W(CO)6] may be used as a precursor for the deposition of WO3-x films, which may be used as gas sensors for the detection of NO2. [2]

Piktogramme

Skull and crossbones
GHS06

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral

Lagerklassenschlüssel

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Eyeshields, Gloves, type N95 (US)

Hier finden Sie alle aktuellen Versionen:

Analysenzertifikate (COA)

Lot/Batch Number
MKCX1551
MKCW2230
MKCW2233
MKCT8273
MKCV4578

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Benzolchrom(0)-tricarbonyl 98%

Sigma-Aldrich

119318

Benzolchrom(0)-tricarbonyl

Hexacarbonylmolybdenum for synthesis

Sigma-Aldrich

8.00396

Hexacarbonylmolybdenum

Dipankar Srimani et al.
Organic letters, 9(18), 3639-3642 (2007-08-07)
An efficient synthesis of Pd nanoparticles in water has been developed using a Fischer carbene complex of tungsten as the reductant and PEG as the capping agent. The colloidal palladium (1 mol %) efficiently catalyzes Hiyama cross-coupling reactions performed in
Aerosol assisted chemical vapour deposition of WO 3 thin films from tungsten hexacarbonyl and their gas sensing properties.
Ashraf S, et al.
Journal of Materials Chemistry, 17.35, 3708-3713 (2007)
F Porrati et al.
Nanotechnology, 20(19), 195301-195301 (2009-05-08)
W-based granular metals have been prepared by electron-beam-induced deposition from the tungsten hexacarbonyl W(CO)(6) precursor. In situ electrical conductivity measurements have been performed to monitor the growth process and to investigate the behavior of the deposit under electron beam post-irradiation
S Martin et al.
The Journal of chemical physics, 134(3), 034304-034304 (2011-01-26)
We have studied the excitation and dissociation processes of the molecule W(CO)(6) in collisions with low kinetic energy (3 keV) protons, monocharged fluorine, and chlorine ions using double charge transfer spectroscopy. By analyzing the kinetic energy loss of the projectile
Seth M Dumbris et al.
The Journal of organic chemistry, 74(22), 8862-8865 (2009-10-30)
Hydantoins can be synthesized from the corresponding amino amides employing oxidative catalytic carbonylation using W(CO)(6) as the catalyst, I(2) as the oxidant, CO as the carbonyl source, and DBU as base. Secondary amides afford the hydantoins in good to excellent
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      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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