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383074

Sigma-Aldrich

硝酸铋(III) 五水合物

ACS reagent, ≥98.0%

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About This Item

線性公式:
Bi(NO3)3 · 5H2O
CAS號碼:
分子量::
485.07
EC號碼:
分類程式碼代碼:
12352302
PubChem物質ID:
NACRES:
NB.24
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等級

ACS reagent

品質等級

化驗

≥98.0%

形狀

(Powder or Crystals or Solid or Chunks)

反應適用性

reagent type: catalyst
core: bismuth

雜質

≤0.005% insolubles

bp

75-80 °C (lit.)

mp

30 °C (lit.)

負離子痕跡

chloride (Cl-): ≤0.001%
sulfate (SO42-): ≤0.005%

正離子痕跡

Ag: ≤0.001%
As: ≤0.001%
Ca: ≤0.005%
Cu: ≤0.002%
Fe: ≤0.001%
K: ≤0.01%
Na: ≤0.02%
Pb: ≤0.002%

SMILES 字串

O=[N+](O[Bi](O[N+]([O-])=O)O[N+]([O-])=O)[O-].C

InChI

1S/CH4.Bi.3NO3/c;;3*2-1(3)4/h1H4;;;;/q;+3;3*-1

InChI 密鑰

DPLOIMSBRDLLRI-UHFFFAOYSA-N

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一般說明

硝酸铋 (Ⅲ) 五水合物是一种无毒、价廉、易操作且对空气不敏感的试剂,常用于有机合成中,具有广泛的应用前景。[1]

應用

硝酸铋 (III) 五水合物可用于以下工艺:
  • 硫代酰胺和硫脲类化合物转化成它们的氧衍生物。[2]
  • 在微波和无溶剂条件下芳香醛转化为羧酸。[3]
  • 在无溶剂条件下通过Pechmann缩合合成香豆素。[1]
  • 作为纯镧改性铋铁氧体(BFO)陶瓷合成的前体。[4]
  • 微波辐射下合成甲基硝基-2,4,6-三硝基苯的硝化剂。[5]
  • 作为制备 4-氨基-5-嘧啶腈和嘧啶酮衍生物的催化剂。[6]
  • 通过未保护的糖的Fischer糖基化合成糖苷。[7]
  • 氧化铋(Bi2O3)纳米粒子的合成。[8]
  • 4-替代 Hantzsch 1,4-二氢吡啶的氧化。[9]
  • 硫醚选择氧化成亚砜。[10]

象形圖

Flame over circleCorrosion

訊號詞

Danger

危險聲明

危險分類

Eye Dam. 1 - Ox. Sol. 2

儲存類別代碼

5.1B - Oxidizing hazardous materials

水污染物質分類(WGK)

WGK 2

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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分析證明 (COA)

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存取文件庫

Bismuth (III) nitrate pentahydrate: a convenient and selective reagent for conversion of thiocarbonyls to their carbonyl compounds.
Mohammadpoor-Baltork I, et al.
Tetrahedron Letters, 44(3), 591-594 (2003)
Bismuth Nitrate Pentahydrate: A Convenient Reagent for the Oxidation of Hantzsch 1,4-Dihydropyridines.
Mashraqui SH and Karnik MA.
Synthesis, 1998(5), 713-714 (1998)
Preparation of lead-free nanoglass frit powder for crystalline silicon solar cells.
Che Q, et al.
Applied Energy, 112, 657-662 (2013)
Bismuth (III) nitrate pentahydrate: a stoichiometric reagent for microwave induced mild and highly efficient aerial oxidation of aromatic aldehydes under solvent-free conditions.
Mukhopadhyay C and Datta A.
Catalysis Communications, 9(15), 2588-2592 (2008)
Facile synthesis of bismuth oxide nanoparticles by a hydrolysis solvothermal route and their visible light photocatalytic activity.
Luan X, et al.
Environmental Engineering and Management Journal, 14(3), 703-707 (2015)

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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