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248592

Sigma-Aldrich

硝酸铋(III) 五水合物

reagent grade, 98%

同義詞:

Bismuth trinitrate pentahydrate

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About This Item

線性公式:
Bi(NO3)3 · 5H2O
CAS號碼:
10035-06-0
分子量：:
485.07
EC號碼:
233-791-8
分類程式碼代碼:
12161600
PubChem物質ID:
24854938
NACRES:
NA.22
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等級

reagent grade

品質等級

100

化驗

98%

形狀

crystals

反應適用性

core: bismuth
reagent type: catalyst

bp

75-80 °C (lit.)

mp

30 °C (lit.)

SMILES 字串

O=[N+](O[Bi](O[N+]([O-])=O)O[N+]([O-])=O)[O-].C

InChI

1S/CH4.Bi.3NO3/c;;3*2-1(3)4/h1H4;;;;/q;+3;3*-1

InChI 密鑰

DPLOIMSBRDLLRI-UHFFFAOYSA-N

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相關類別

一般說明

硝酸铋（III） 五水合物是水合形式的硝酸铋（III）。它可作为有效的路易斯酸催化剂用于硫代羰基转化为羰基化合物的有机合成反应；芳香硝化反应；羰基化合物的保护；Michael反应和香豆素的合成。

應用

各种 4-取代的 Hantzsch 1,4-二氢吡啶的优质氧化剂。[1]将硫化物选择性氧化成亚砜的简便试剂。[2]

象形圖

Flame over circleCorrosion
GHS03,GHS05

訊號詞

Danger

危險聲明

H272,H318

危險分類

Eye Dam. 1 - Ox. Sol. 2

儲存類別代碼

5.1B - Oxidizing hazardous materials

水污染物質分類（WGK）

WGK 2

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

從最近期的版本中選擇一個：

分析證明 (COA)

Lot/Batch Number
MKCW6283
MKCW7693
MKCV6868
MKCQ5584
MKCS6602

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存取文件庫

Mashraqui, S.H. et al.
Synthetic Communications, 28, 939-939 (1998)
Mashraqui, S.H. Karnik, M.A.
Synthesis, 713-713 (1998)
Na Li et al.
Dalton transactions (Cambridge, England : 2003), 43(36), 13742-13750 (2014-08-12)
The xFe2O3/yBiOCl composites (xFe/yBi, x/y = 0/100, 5/100, 10/100, 20/100, 30/100 and 40/100 molar ratios) are prepared for the first time through an in situ hydrolysis method under hydrothermal conditions. The samples are characterized by X-ray diffraction (XRD), scanning electron
Nahid Gharib Naseri et al.
Analytical and bioanalytical chemistry, 391(4), 1283-1292 (2008-03-21)
Catalytic adsorptive stripping voltammetry (CAdSV) has been demonstrated at a bismuth film electrode (BiFE) in an injection-moulded electrochemical micro-flow cell. The polystyrene three-electrode flow cell was fabricated with electrodes moulded from a conducting grade of polystyrene containing 40% carbon fibre
Marcela Luísa Gomes et al.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry, 20(5), 771-779 (2015-05-02)
Two bismuth(III) porphyrins-5,10,15,20-tetrakis(phenyl)porphyrinatobismuth(III) nitrate, [Bi(III)(TPP)]NO3, and the unprecedent 5,10,15,20-tetrakis(4-carbomethoxyphenyl)porphyrinatobismuth(III) nitrate, [Bi(III)(T4CMPP)]NO3, and two unprecedented antimony(V) porphyrins dichlorido(5,10,15,20-tetrakis(phenyl)porphyrinato)antimony(V) bromide, [Sb(V)(TPP)Cl2]Br, and dibromido(5,10,15,20-tetrakis(4-carbomethoxyphenyl)porphyrinato)antimony(V) bromide, [Sb(V)(T4CMPP)Br2]Br,-were synthesized by reacting the corresponding porphyrin ligand with Bi(NO3)3·5H2O or SbCl3. All compounds were characterized by UV-vis
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    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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