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326755

Sigma-Aldrich

乙酸铜

greener alternative

98%

同義詞:

醋酸铜

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About This Item

線性公式:
Cu(CO2CH3)2
CAS號碼:
分子量::
181.63
Beilstein:
3595638
EC號碼:
MDL號碼:
分類程式碼代碼:
12352302
PubChem物質ID:
NACRES:
NA.22

蒸汽密度

6.9 (vs air)

化驗

98%

形狀

powder or crystals

反應適用性

reaction type: click chemistry

環保替代產品特色

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

環保替代類別

SMILES 字串

CC(=O)O[Cu]OC(C)=O

InChI

1S/2C2H4O2.Cu/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2

InChI 密鑰

OPQARKPSCNTWTJ-UHFFFAOYSA-L

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相關類別

一般說明

我们致力于为您提供更环保的替代产品,以符合“绿色化学的12项原则”的一项或多项原则要求。该产品为增强型,提高了催化效率。点击此处获取更多信息。

乙酸铜又名醋酸铜,在绿色化学领域,可用作多种过程的催化剂。尤其在交叉偶联反应中可促进碳-碳键或碳-杂原子键形成,而无需添加有害试剂或溶剂。

應用

氢气还原胺化反应合成胺这种绿色方法的催化剂。

使用环保的分子氢完成铜催化的芳酮和脂酮与苯胺的还原胺化反应

醋酸铜用作催化剂:
  • 用于α-氨基酯和对甲基苯硼酸经交叉偶联反应N-芳基化为双芳基
  • 用于取代异噁唑衍生物的合成

訊號詞

Danger

危險聲明

危險分類

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B

儲存類別代碼

8B - Non-combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

does not flash

閃點(°C)

does not flash

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


分析證明 (COA)

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存取文件庫

An efficient synthesis of novel isoxazole bearing pyrazole derivatives via [3+ 2] heteroannulation using cupric acetate
B Audichya, et al.
Journal of Heterocyclic Chemistry, 59, 341-350 (2022)
N-Arylation of ?-aminoesters with p-tolylboronic acid promoted by copper (II) acetate
PYS Lam, et al.
Tetrahedron Letters, 44, 1691-1694 (2003)
Heather A Michaels et al.
Chemistry, an Asian journal, 6(10), 2825-2834 (2011-09-29)
Polytriazole ligands such as the widely used tris[(1-benzyl-1H-1,2,3-triazol-4-yl)methyl]amine (TBTA), are shown to assist copper(II) acetate-mediated azide-alkyne cycloaddition (AAC) reactions that involve nonchelating azides. Tris(2-{4-[(dimethylamino)methyl]-1H-1,2,3-traizol-1-yl}ethyl)amine (DTEA) outperforms TBTA in a number of reactions. The satisfactory solubility of DTEA in a wide
Anitha M Thomas et al.
Journal of controlled release : official journal of the Controlled Release Society, 150(2), 212-219 (2010-11-26)
5-Fluorouracil (5-FU) is a small, very membrane permeable drug that is poorly retained within the aqueous compartment of liposomal nanoparticles (LNP). To address this problem a novel method relying on formation of a ternary complex comprising copper, low molecular weight
Cinthia da S Lisboa et al.
The Journal of organic chemistry, 76(13), 5264-5273 (2011-05-25)
The oxidative addition of anilines (2) with 1,4-naphthoquinone (3) to give N-aryl-2-amino-1,4-naphthoquinones (1) was found to be catalyzed by copper(II) acetate. In the absence of the catalyst, the reactions are slower and give lower yields with the formation of many

文章

Copper metal deposition processes are an essential tool for depositing interconnects used in microelectronic applications, giving group 11 (coinage metals: Copper, Silver, and Gold) an important place in atomic layer deposition (ALD) process development.

利用 Cu(I)-catalyzed Huisgen 1,3-dipolar cycloaddition of terminal alkynes 與 organoazides 的化學反應生成 1,4-disubstituted 1,2,3-triazoles 的藥物發現過程。

Drug discovery process by utilizing chemistry reaction of Cu(I)-catalyzed Huisgen 1,3-dipolar cycloaddition of terminal alkynes with organoazides to yield 1,4-disubstituted 1,2,3-triazoles.

我們的科學家團隊在所有研究領域都有豐富的經驗,包括生命科學、材料科學、化學合成、色譜、分析等.

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