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Sigma-Aldrich

氯化铋 (III)

reagent grade, ≥98%

同義詞:

三氯化铋, 三氯铋

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About This Item

經驗公式（希爾表示法）:
BiCl3
CAS號碼:
7787-60-2
分子量：:
315.34
EC號碼:
232-123-2
MDL號碼:
MFCD00003461
分類程式碼代碼:
12352302
PubChem物質ID:
57647987
NACRES:
NA.21
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等級

reagent grade

品質等級

100

化驗

≥98%

形狀

powder, chunks or granules

反應適用性

reagent type: catalyst
core: bismuth

bp

447 °C (lit.)

mp

230-232 °C (lit.)

SMILES 字串

Cl[Bi](Cl)Cl

InChI

1S/Bi.3ClH/h;3*1H/q+3;;;/p-3

InChI 密鑰

JHXKRIRFYBPWGE-UHFFFAOYSA-K

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相關類別

一般說明

氯化铋 (III) 是一种无机盐，可由铋与氯反应制得。 [1]

應用

氯化铋 (III) 可作为催化剂用于以下过程：
  • 醇解、乙酰化和环氧化物水解生成相应的的 β-烷氧基和 β-乙酰氧基醇和二醇。[2]
  • 用硫氰酸铵从环氧乙烷制备噻吩。[3]
  • 羰基化合物、胺和亚磷酸二烷基酯三组分偶联生成 α-氨基膦酸盐。[4]
  • 烯丙基三甲基硅烷与仲苯甲醇的烯丙基化反应。[5]
  • [4 + 2] 二烯烃与α-羰基烯二烯烃之间的环加成反应。[6]

象形圖

Exclamation mark
GHS07

訊號詞

Warning

危險聲明

H315,H319

危險分類

Eye Irrit. 2 - Skin Irrit. 2

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 2

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves

從最近期的版本中選擇一個：

分析證明 (COA)

Lot/Batch Number
0000323952
0000323952
0000293124
0000252089
0000293124

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Daintith J
The facts on file dictionary of chemistry, 28-28 (2014)
Bismuth (III) chloride-catalyzed direct deoxygenative allylation of substituted benzylic alcohols with allyltrimethylsilane
De SK & Gibbs RA.
Tetrahedron Letters, 46(48), 8345-8350 (2005)
Bismuth (III) chloride (BiCl3)-An efficient catalyst for mild, regio-and stereoselective cleavage of epoxides with alcohols, acetic Acid and water.
Mohammadpoor-Baltork I.
Synthetic Communications, 30(13), 2365-2374 (2000)
Bismuth (III) Chloride-Catalyzed Three-Component Coupling: Synthesis of a-Amino Phosphonates.
Zhan ZP and Li JP.
Synthetic Communications, 35(19), 2501-2508 (2005)
Bismuth (iii) Chloride Mediated Michaelis-Arbuzov Reaction: A Facile Synthesis of Substituted Arylphosphonates/Phosphinates and Bioactivity Evaluation.
Subramanyam C, et al.
Phosph. Sulfur Relat. Elem. (2015)
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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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