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901409

Sigma-Aldrich

[铱 (dF (Me) ppy)] 2 (dtbbpy) ] PF 6

同義詞:

铱 (III) 双 [2-（2,4-二氟苯基）-5-甲基吡啶- N ,C 20 ]-4,40-二- 叔 -丁基-2,20-二吡啶六氟磷酸盐

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About This Item

經驗公式（希爾表示法）:
C42H40F10IrN4P
CAS號碼:
1335047-34-1
分子量：:
1013.97
MDL號碼:
MFCD31619196
分類程式碼代碼:
12161600
NACRES:
NA.22
暫時無法取得訂價和供貨情況

形狀

solid

品質等級

100

反應適用性

core: iridium
reaction type: Photocatalysis
reagent type: catalyst

活化光觸媒

450 nm

InChI 密鑰

XAJPUJWOMJJPNU-UHFFFAOYSA-N

相關類別

應用

[Ir (dF (Me) ppy)] 2 (dtbbpy) ] PF 6 是一种光催化剂，容易促进烯烃的加氢胺化反应，也容易促进羧酸的脱羧芳基化反应和乙烯基化反应（通过金属卟啉催化）。

产品可与我们的光反应器系列一起使用：包括Penn PhD（Z744035）& SynLED 2.0 （Z744080）

其他說明

仲烃胺催化未活化烯烃的分子间氢化反应

光还原与镍催化的结合：羧酸与卤化乙烯的脱羧交叉偶联

含芳基三唑环金属配体的增强发光铱 (III) 配合物

二芳基硼酸和光还原组合催化的碳水化合物 C-H 烷基化反应

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儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

從最近期的版本中選擇一個：

分析證明 (COA)

Lot/Batch Number
MKCQ2750
MKCJ5323
MKCK6936

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Victoria Dimakos et al.
Journal of the American Chemical Society, 141(13), 5149-5153 (2019-03-23)
Diphenylborinic acid serves as a cocatalyst for site- and stereoselective C-H alkylation reactions of carbohydrates under photoredox conditions using quinuclidine as the hydrogen atom transfer mediator. Products arising from selective abstraction of the equatorial hydrogens of cis-1,2-diol moieties, followed by
Adam Noble et al.
Journal of the American Chemical Society, 137(2), 624-627 (2014-12-19)
Decarboxylative cross-coupling of alkyl carboxylic acids with vinyl halides has been accomplished through the synergistic merger of photoredox and nickel catalysis. This new methodology has been successfully applied to a variety of α-oxy and α-amino acids, as well as simple
Andrew J Musacchio et al.
Science (New York, N.Y.), 355(6326), 727-730 (2017-02-18)
The intermolecular hydroamination of unactivated alkenes with simple dialkyl amines remains an unsolved problem in organic synthesis. We report a catalytic protocol for efficient additions of cyclic and acyclic secondary alkyl amines to a wide range of alkyl olefins with
Sébastien Ladouceur et al.
Inorganic chemistry, 50(22), 11514-11526 (2011-10-04)
Herein we report the synthesis of 4-aryl-1-benzyl-1H-1,2,3-triazoles (atl), made via "Click chemistry" and their incorporation as cyclometallating ligands into new heteroleptic iridium(III) complexes containing diimine (N(^)N) ancillary ligands 2,2'-bipyridine (bpy) and 4,4'-di-tert-butyl-2,2'-bipyridine (dtBubpy). Depending on decoration, these complexes emit from
Strongly Blue Luminescent Cationic Iridium(III) Complexes with an Electron-Rich Ancillary Ligand: Evaluation of Their Optoelectronic and Electrochemiluminescence Properties.
Ladouceur S, et al.
European Journal of Inorganic Chemistry, 2013(30), 5329-5343 (2013)
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