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747793

Sigma-Aldrich

(Ir[dF(CF3)ppy]2(dtbpy))PF6

同義詞:

（Ir{dF（CF3）PPY}2（dtbpy））PF6, [4,4′-双（1,1-二甲基乙基）-2,2′-联吡啶N1，N1']双[3,5-二氟-2- [5-（三氟甲基）-2-吡啶基N]苯基-C]六氟磷酸铱（III）

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About This Item

經驗公式（希爾表示法）:
C42H34F16IrN4P
CAS號碼:
870987-63-6
分子量：:
1121.91
MDL號碼:
MFCD27952556
分類程式碼代碼:
12161600
NACRES:
NA.22
暫時無法取得訂價和供貨情況

形狀

solid

品質等級

100

反應適用性

core: iridium
reagent type: catalyst
reaction type: Photocatalysis

mp

>300 °C

活化光觸媒

450 nm

SMILES 字串

F[P](F)(F)(F)(F)F.CC(C)(C)C1=CC=[N@H]2C(=C1)C3=CC(=CC=[N@@H]3[Ir]2456c7cc(F)cc(F)c7C8=CC=C(C=[N]48)C(F)(F)F)C(C)(C)C.Fc9cc(F)c(C%10=[N]5C=C(C=C%10)C(F)(F)F)c6c9

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相關類別

應用

（Ir[DF（CF3）PPY]2（dtbpy））PF6 是一种环金属化的铱（III）配合物，可用于可见光介导的光催化有机转化。[1][2][3][4][5]它可用于将烷基通过后期结合至多种生物活性杂环中。[3]

产品可与我们的光反应器系列一起使用。包括Penn PhD（Z744035）& SynLED 2.0 （Z744080）

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

從最近期的版本中選擇一個：

分析證明 (COA)

Lot/Batch Number
0000408277
0000377736
0000338360
0000305691
0000377736

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A photochemical strategy for lignin degradation at room temperature.
Nguyen J D, et al.
Journal of the American Chemical Society, 136(4), 1218-1221 (2014)
Advances in Photocatalysis: A Microreview of Visible Light Mediated Ruthenium and Iridium Catalyzed Organic Transformations.
Teegardin K, et al.
Organic Process Research & Development, 20(7), 1156-1163 (2016)
Formal Total Synthesis of l-Ossamine via Decarboxylative Functionalization Using Visible-Light-Mediated Photoredox Catalysis in a Flow System.
Inuki S, et al.
The Journal of Organic Chemistry, 82(2), 1248-1253 (2017)
Radical Carbon?Carbon Bond Formations Enabled by Visible Light Active Photocatalysts.
Wallentin C J, et al.
Chimia, 66(6), 394-398 (2012)
Late?Stage Functionalization of Biologically Active Heterocycles Through Photoredox Catalysis.
DiRocco D A et al.
Angewandte Chemie (International Edition in English), 53(19), 4802-4806 (2014)

相關內容

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Research in the Stephenson lab focuses upon the development of new chemical methods which enable the activation of chemical bonds under mild reaction conditions.

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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