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723142

Sigma-Aldrich

三[2-(二甲氨基)乙基]胺

97%

同義詞:

Me6TREN

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About This Item

經驗公式(希爾表示法):
C12H30N4
CAS號碼:
分子量::
230.39
MDL號碼:
分類程式碼代碼:
12162002
PubChem物質ID:
NACRES:
NA.23
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品質等級

化驗

97%

形狀

liquid

折射率

n20/D 1.455

密度

0.862 g/mL at 25 °C

SMILES 字串

CN(C)CCN(CCN(C)C)CCN(C)C

InChI

1S/C12H30N4/c1-13(2)7-10-16(11-8-14(3)4)12-9-15(5)6/h7-12H2,1-6H3

InChI 密鑰

VMGSQCIDWAUGLQ-UHFFFAOYSA-N

一般說明

三[2-(二甲基氨基)乙基]胺(Me6TREN)是形成四齿配体的脂肪族叔胺。这种成分主要用于原子转移自由基聚合(ATRP)。它是(2-氨基乙基)胺的六甲基衍生物,也称为trenMe。可通过修饰Ristempart合成制备这一成分。[1][2][3][4]

應用

Me6TREN与铜化合物形成络合物,可用作金属酶氧化还原反应中的配体。[5]
用于生产遥爪聚合物的原子转移自由基聚合反应(ATRP)配体。[6][7][8][9]

象形圖

Corrosion

訊號詞

Danger

危險聲明

危險分類

Eye Dam. 1 - Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

219.9 °F - closed cup

閃點(°C)

104.4 °C - closed cup


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存取文件庫

Diminishing catalyst concentration in atom transfer radical polymerization with reducing agents
Matyjaszewski K, et al.
Proceedings of the National Academy of Sciences of the USA, 103(42), 15309-15314 (2006)
Optimization of atom transfer radical polymerization using Cu (I)/tris (2-(dimethylamino) ethyl) amine as a catalyst
Queffelec J, et al.
Macromolecules, 33(23), 8629-8639 (2000)
Trigonal bipyramidal complexes of bivalent manganese, iron, and zinc with tris (2-dimethylaminoethyl) amine
Ciampolini Mt and Nardi N
Inorganic Chemistry, 5(7), 1150-1154 (1966)
Tsarevsky, N. V.; Braunecker, W. A.; Brooks, S. J.; Matyjaszewski, K.
Marcromolecules, 39, 6817-6817 (2006)
Expanding the scope of the photoinduced living radical polymerization of acrylates in the presence of CuBr2 and Me6-Tren
Anastasaki A, et al.
Macromolecules, 47(12), 3852-3859 (2014)

文章

查找如何利用原子转移自由基聚合(ATRP)工具合成明确的官能化聚合物。

ATRP is a successful method for precise polymer synthesis with controlled molecular weights and high chain end functionalities.

Micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization.

條款

本文介紹 CSIRO 研究人員聚合甲基丙烯酸甲酯和醋酸乙烯酯均聚物及嵌段共聚物的程序。

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

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相關內容

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

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