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重要文件

366404

Sigma-Aldrich

1,1,4,7,10,10-六甲基三亚乙基四胺

97%

同義詞:

HMTETA

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About This Item

線性公式:
[(CH3)2NCH2CH2N(CH3)CH2-]2
CAS號碼:
分子量::
230.39
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22
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品質等級

化驗

97%

形狀

liquid

折射率

n20/D 1.456 (lit.)

bp

130 °C/11 mmHg (lit.)

密度

0.847 g/mL at 25 °C (lit.)

官能基

amine

SMILES 字串

CN(C)CCN(C)CCN(C)CCN(C)C

InChI

1S/C12H30N4/c1-13(2)7-9-15(5)11-12-16(6)10-8-14(3)4/h7-12H2,1-6H3

InChI 密鑰

DWFKOMDBEKIATP-UHFFFAOYSA-N

一般說明

1,1,4,7,10,10-六甲基三乙烯四胺是一种多胺添加剂,已被报告为问题 Koenigs-Knorr 葡萄糖醛酸化的有效试剂。[1]

應用

1,1,4,7,10,10-六甲基三乙烯四胺可用来合成理想的线性无规共聚物。[2]1,1,4,7,10,10-六甲基三乙烯四胺与 CuBr 形成催化络合物,用于原子转移自由基聚合法 (ATRP) 合成聚 [ε-己内酯] 与 N,N-二甲氨基-2-乙基甲基丙烯酸酯单体。[3]它可以作为水溶液中的催化剂,在表面引发的 ATRP 中生成聚 N,N -二甲基丙烯酰胺 (PDMA)。[4]

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

215.6 °F - closed cup

閃點(°C)

102 °C - closed cup

個人防護裝備

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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Stefanie L Baker et al.
Nature communications, 10(1), 4718-4718 (2019-10-19)
Almost all commercial proteins are purified using ammonium sulfate precipitation. Protein-polymer conjugates are synthesized from pure starting materials, and the struggle to separate conjugates from polymer, native protein, and from isomers has vexed scientists for decades. We have discovered that
Bryan R Coad et al.
Langmuir : the ACS journal of surfaces and colloids, 23(23), 11791-11803 (2007-10-11)
We report the use of aqueous surface-initiated atom transfer radical polymerization (SI-ATRP) to grow polymer brushes from a "gigaporous" polymeric chromatography support for use as a novel size exclusion chromatography medium. Poly(N,N-dimethylacrylamide) (PDMA) was grown from hydrolyzable surface initiators via
Laetitia Mespouille et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 14(21), 6369-6378 (2008-06-10)
Adaptive and amphiphilic poly(N,N-dimethylamino-2-ethyl methacrylate-graft-poly[epsilon-caprolactone]) co-networks (netP(DMAEMA-g-PCL)) were synthesized from a combination of controlled polymerization techniques. Firstly, PCL cross-linkers were produced by ring-opening polymerization (ROP) of epsilon-CL initiated by 1,4-butane-diol and catalyzed by tin(II) 2-ethylhexanoate ([Sn(Oct)2]), followed by the quantitative
Weihang Ji et al.
Biomacromolecules, 18(8), 2583-2593 (2017-06-29)
Antibacterial polymers are potentially powerful biocides that can destroy bacteria on contact. Debate in the literature has surrounded the mechanism of action of polymeric biocides and the propensity for bacteria to develop resistance to them. There has been particular interest
Masato Mizutani et al.
Journal of the American Chemical Society, 132(21), 7498-7507 (2010-05-12)
All polymerization reactions are categorized into two large different families, chain- and step-growth polymerizations, which are typically incompatible. Here, we report the simultaneous chain- and step-growth polymerization via the metal-catalyzed radical copolymerization of conjugated vinyl monomers and designed monomers possessing

文章

Micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization.

條款

本文介紹 CSIRO 研究人員聚合甲基丙烯酸甲酯和醋酸乙烯酯均聚物及嵌段共聚物的程序。

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

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相關內容

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

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