365270

α-溴苯乙酸甲酯

97%

• 線性公式: C₆H₅CH(Br)CO₂CH₃
• CAS號碼: 3042-81-7
• 分子量：: 229.07
• MDL號碼: MFCD00013535
• 分類程式碼代碼: 12352100
• PubChem物質ID: 24862500
• NACRES: NA.22

屬性

• 品質等級: 200
• 化驗: 97%
• 形狀: liquid
• 折射率: n20/D 1.553 (lit.)
• bp: 113 °C/3 mmHg (lit.)
• 密度: 1.455 g/mL at 25 °C (lit.)
• 官能基: bromo; ester; phenyl
• 儲存溫度: 2-8°C
• SMILES 字串: COC(=O)C(Br)c1ccccc1
• InChI: 1S/C9H9BrO2/c1-12-9(11)8(10)7-5-3-2-4-6-7/h2-6,8H,1H3
• InChI 密鑰: NHFBYYMNJUMVOT-UHFFFAOYSA-N

描述

一般說明

Methyl α-bromophenylacetate is an ester. Palladium catalyzed homocoupling reaction of methyl α-bromophenylacetate with 3,5-dimethyl phenyl boronic acid is reported.[1]

應用

Methyl α-bromophenylacetate may be used as initiator during ESR study of atom transfer radical polymerization (ATRP) of methyl methacrylate (MMA) and ethylene glycol dimethacrylate (EGDMA).[2] It may be used as reagent in the homopolymerization of MMA in supercritical carbon dioxide.[3]

安全資訊

• 象形圖: GHS05
• 訊號詞: Danger
• 危險聲明: H314
• 防範說明: P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363 - P405
• 危險分類: Skin Corr. 1B
• 儲存類別代碼: 8A - Combustible corrosive hazardous materials
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: 235.4 °F - closed cup
• 閃點（°C）: 113 °C - closed cup
• 個人防護裝備: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter