903973

Thianthrene S-oxide

≥95%

• Synonim(y): Non-fluorinated sulfoxide-based thianthrene reagent, Thianthrene 5-oxide
• Wzór empiryczny (zapis Hilla): C₁₂H₈OS₂
• Numer CAS: 2362-50-7
• Masa cząsteczkowa: 232.32
• Numer MDL: MFCD01464038
• Kod UNSPSC: 12352119
• NACRES: NA.22

Właściwości

• Próba: ≥95%
• Postać: powder
• temp. przechowywania: 2-8°C
• InChI: 1S/C12H8OS2/c13-15-11-7-3-1-5-9(11)14-10-6-2-4-8-12(10)15/h1-8H
• Klucz InChI: NYVGTLXTOJKHJN-UHFFFAOYSA-N

Opis

Zastosowanie

Thianthrene S-oxide is a sulfoxide-based thianthrene reagent for late-stage C-H functionalization. Developed by the Ritter Lab, C-H functionalization by thianthrenation proceeds with >99% selectivity and furnishes functionalized arenes serving as synthetic linchpins for further participation in diverse transformations. Nonfluorinated thianthrene S-oxide is best used for all arenes more electron-rich than anisole. For other arenes, the fluorinated TFT S-oxide (903981) was demonstrated as the thanthrenation reagent.

Inne uwagi

Site-selective and versatile aromatic C-H functionalization by thianthrenation

Video: Site-selective C-H functionalization by thianthrenation

In the Pipeline: New Chemistry, Making New Things

Ti(Phen)(OC₂H₅)₂Cl₂: a highly efficient pre-?catalyst for selective oxidation of organic sulfides to sulfoxides by hydrogen peroxide

Informacje prawne

Patent Application EP18204755.5
This product is manufactured pursuant to a license with Studiengesellschaft Kohle mbH

Informacja o środkach bezpieczeństwa

• Kod klasy składowania: 11 - Combustible Solids
• Klasa zagrożenia wodnego (WGK): WGK 3
• Temperatura zapłonu (°F): Not applicable
• Temperatura zapłonu (°C): Not applicable