397229

アセトアニリド

purified by sublimation, ≥99.9%

• 別名: N-フェニルアセトアミド
• 化学式: CH₃CONHC₆H₅
• CAS番号: 103-84-4
• 分子量: 135.16
• Beilstein: 606468
• EC Number: 203-150-7
• MDL番号: MFCD00008674
• UNSPSCコード: 12352100
• eCl@ss: 39031308
• PubChem Substance ID: 24864694
• NACRES: NA.22

特性

• 蒸気密度: 4.65 (vs air)
• 蒸気圧: 1 mmHg ( 114 °C)
• アッセイ: ≥99.9%
• 形状: solid
• 自己発火温度: 1004 °F
• 精製方法: sublimation
• bp: 304 °C (lit.)
• mp: 113-115 °C (lit.)
• SMILES記法: CC(=O)Nc1ccccc1
• InChI: 1S/C8H9NO/c1-7(10)9-8-5-3-2-4-6-8/h2-6H,1H3,(H,9,10)
• InChI Key: FZERHIULMFGESH-UHFFFAOYSA-N

詳細

詳細

Pd(OAc)₂ and Cu(OAc)₂ catalyzed regioselective C-H functionalization/halogenation of acetanilide has been reported to afford ortho-haloacetanilides. Crystal structure of acetanilide has been studied by X-ray diffraction. Photorearrangement of acetanilide has been studied in the presence of β-cyclodextrin (cycloheptaamylose). Two-color REMPI (resonance enhanced multiphoton ionization) and ZEKE (zero kinetic energy photoelectron) spectra of the trans-acetanilide·H₂O complex has been reported. Femtosecond IR spectroscopy of delocalized NH excitations of crystalline acetanilide has been studied. Fries rearrangement of acetanilide over zeolites Y and Beta affords corresponding aminoacetophenones.

安全性情報

• ピクトグラム: GHS07
• シグナルワード: Warning
• 危険有害性情報: H302
• 注意書き: P264 - P270 - P301 + P312 - P501
• 危険有害性の分類: Acute Tox. 4 Oral
• 保管分類コード: 11 - Combustible Solids
• WGK: WGK 1
• 引火点(°F): 321.8 °F - closed cup
• 引火点(℃): 161 °C - closed cup
• 個人用保護具 (PPE): dust mask type N95 (US), Eyeshields, Gloves