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25 ML
￥9,050
100 ML
￥32,300
About This Item
化学式:
CH3(CH2)4COCl
CAS番号:
分子量:
134.60
Beilstein:
506332
EC Number:
MDL番号:
UNSPSCコード:
12352100
PubChem Substance ID:
NACRES:
NA.22
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品質水準
アッセイ
≥99%
屈折率
n20/D 1.426 (lit.)
bp
150-153 °C (lit.)
密度
0.963 g/mL at 25 °C (lit.)
官能基
acyl chloride
SMILES記法
CCCCCC(Cl)=O
InChI
1S/C6H11ClO/c1-2-3-4-5-6(7)8/h2-5H2,1H3
InChI Key
YWGHUJQYGPDNKT-UHFFFAOYSA-N
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関連するカテゴリー
アプリケーション
Hexanoyl chloride has been used in:
- total synthesis of (±)-7-butyl-6,8-dihydroxy-3-pentyl-3,4-dihydroisochromen-1-one[1]
- asymmetric synthesis of 14-methyl-1-octadecene, the sex pheromone of the peach leafminer moth[2]
- preparation of hexanoyl-coated nanofibers dispersible in several organic solvents[3]
- total synthesis of natural isocarbostyril ruprechstyril (3-n-pentyl-6-methoxy-8-hydroxy-1(2H)-isoquinolinone), isolated from Ruprechtia tangarana[4]
- 5-chloro-8-hydroxy-6-methoxy-3-pentylisocoumarin, the 5-chloro analog of naturally occurring 7-chloro-8-hydroxy-6-methoxy-3-pentylisocoumarin, isolated from Tessmannia densiflora[5]
シグナルワード
Danger
危険有害性情報
危険有害性の分類
Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B
保管分類コード
3 - Flammable liquids
WGK
WGK 1
引火点(°F)
122.0 °F - closed cup
引火点(℃)
50 °C - closed cup
個人用保護具 (PPE)
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
適用法令
試験研究用途を考慮した関連法令を主に挙げております。化学物質以外については、一部の情報のみ提供しています。 製品を安全かつ合法的に使用することは、使用者の義務です。最新情報により修正される場合があります。WEBの反映には時間を要することがあるため、適宜SDSをご参照ください。
消防法
第4類:引火性液体
第二石油類
危険等級III
非水溶性液体
Jan Code
294659-25ML:
294659-BULK:
294659-VAR:
294659-100ML:
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Aamer Saeed
Journal of Asian natural products research, 13(6), 505-511 (2011-05-31)
The synthesis of title isocoumarin, the 5-chloro analog of naturally occurring 7-chloro-8-hydroxy-6-methoxy-3-pentylisocoumarin, isolated from Tessmannia densiflora is described. Chlorination of ethyl 2-(2-ethoxy-2-oxoethyl)-4,6-dimethoxybenzoate (2) afforded 3-chloro ester (3) followed by hydrolysis to furnish the 2-(carboxymethyl)-3-chloro-4,6-dimethoxybenzoic acid (4) that was converted to
Tao Zhang et al.
Molecules (Basel, Switzerland), 18(5), 5201-5208 (2013-05-09)
An asymmetric synthesis of 14-methyl-1-octadecene, the sex pheromone of the peach leafminer moth has been achieved. The target molecule was synthesized in six linear steps and in 30.3% overall yield from commercially available hexanoyl chloride, (S)-4-benzyloxazolidin-2-one and 1,9-nonanediol. The hexanoyl
Aamer Saeed
Natural product research, 27(13), 1153-1158 (2012-08-14)
A short total synthesis of natural isocarbostyril ruprechstyril (3-n-pentyl-6-methoxy-8-hydroxy-1(2H)-isoquinolinone) isolated from Ruprechtia tangarana is reported. 6,8-Dimethoxy-3-pentylisocoumarin obtained by condensation of 3,5-dimethoxyhomophthalic anhydride with hexanoyl chloride was smoothly converted to O-methylruprechstyril by refluxing with methanamide. Regioselective demethylation of the latter using
Aamer Saeed et al.
Journal of Asian natural products research, 15(10), 1112-1122 (2013-07-23)
A new total synthesis of ( ± )-7-butyl-6,8-dihydroxy-3-pentyl-3,4-dihydroisochromen-1-one, isolated as R-enantiomer from Geotrichum sp., has been described. Reaction of 4-butyl-3,5-dimethoxyhomophthalic anhydride with hexanoyl chloride in the presence of 1,1,3,3-tetramethyl guanidine and triethyl amine afforded 7-butyl-6,8-dimethoxy-3-pentylisochromen-1-one, which was converted into corresponding 3,4-dihydroisochromen-1-one by
One-step dispersion of cellulose nanofibers by mechanochemical esterification in an organic solvent.
Pei Huang et al.
ChemSusChem, 5(12), 2319-2322 (2012-11-28)
Got a crush: Native cellulose can be dispersed as nanofibers in organic solvents by ball milling with esterification agents. Milling with hexanoyl chloride/DMF gives hexanoyl-coated nanofibers dispersible in several organic solvents. Milling with succinic anhydride/DMSO results water-dispersible nanofibers. The results
アクティブなフィルタ
ライフサイエンス、有機合成、材料科学、クロマトグラフィー、分析など、あらゆる分野の研究に経験のあるメンバーがおります。.
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