124826

4-シアノベンゾイルクロリド

98%

• 別名: 4-Cyanobenzoic acid chloride, p-Cyanobenzoyl chloride
• 化学式: NCC₆H₄COCl
• CAS番号: 6068-72-0
• 分子量: 165.58
• Beilstein: 386729
• EC Number: 228-005-5
• MDL番号: MFCD00001822
• UNSPSCコード: 12352100
• PubChem Substance ID: 24847629
• NACRES: NA.22

特性

• 品質水準: 100
• アッセイ: 98%
• フォーム: solid
• mp: 68-70 °C (lit.)
• 官能基: acyl chloride; nitrile
• SMILES記法: ClC(=O)c1ccc(cc1)C#N
• InChI: 1S/C8H4ClNO/c9-8(11)7-3-1-6(5-10)2-4-7/h1-4H
• InChI Key: USEDMAWWQDFMFY-UHFFFAOYSA-N

詳細

詳細

4-Cyanobenzoyl chloride participates in the benzylamine acylation of Argopore MB-CHO resin in the presence of pyridine and catalyst[1]. It reacts with 4-hydroxy-2,2,6,6-tetramethyl-1-piperidinoxyl (4-hydroxy-TEMPO) in pyridine under nitrogen atmosphere to form 4-cyanobenzoyl-TEMPO[2].

アプリケーション

4-Cyanobenzoyl chloride has been used in the synthesis of new liquid crystalline heteroaromatic compounds containing the five-membered isoxazole, tetrazole and 1,2,4-oxadiazole rings[3]. It has been used in the synthesis of substituted benzoate esters and to study their excited-state behavior[4].

安全性情報

• ピクトグラム: GHS05
• シグナルワード: Danger
• 危険有害性情報: H314
• 注意書き: P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
• 危険有害性の分類: Eye Dam. 1 - Skin Corr. 1B
• 保管分類コード: 8A - Combustible corrosive hazardous materials
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable
• 個人用保護具 (PPE): Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges