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Merck
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Documenti fondamentali

C76604

Sigma-Aldrich

Cholesteryl chloride

97%

Sinonimo/i:

3β-Chloro-5-cholestene

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About This Item

Formula empirica (notazione di Hill):
C27H45Cl
Numero CAS:
Peso molecolare:
405.10
Beilstein:
2703655
Numero CE:
Numero MDL:
Codice UNSPSC:
12352103
ID PubChem:
NACRES:
NA.23

Saggio

97%

Stato

liquid crystal

Attività ottica

[α]25/D −24°, c = 1 in chloroform

Punto di fusione

94-96 °C (lit.)

Stringa SMILE

CC(C)CCC[C@@H](C)[C@H]1CC[C@H]2[C@@H]3CC=C4C[C@@H](Cl)CC[C@]4(C)[C@H]3CC[C@]12C

InChI

1S/C27H45Cl/c1-18(2)7-6-8-19(3)23-11-12-24-22-10-9-20-17-21(28)13-15-26(20,4)25(22)14-16-27(23,24)5/h9,18-19,21-25H,6-8,10-17H2,1-5H3/t19-,21+,22+,23-,24+,25+,26+,27-/m1/s1
OTVRYZXVVMZHHW-DPAQBDIFSA-N

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Codice della classe di stoccaggio

11 - Combustible Solids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

Eyeshields, Gloves, type N95 (US)


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P Oswald
The European physical journal. E, Soft matter, 35(2), 10-10 (2012-02-22)
In a recent letter (EPL 97, 36006 (2012)), we have shown that the Leslie thermomechanical coupling cannot alone explain the Lehmann effect (namely the rotation of cholesteric droplets when they are subjected to a temperature gradient). This result was obtained
N Weber et al.
Food and chemical toxicology : an international journal published for the British Industrial Biological Research Association, 32(4), 297-303 (1994-04-01)
3 beta-Chlorosteroids, such as cholesteryl beta-chloride and sitosteryl beta-chloride, are formed during the production of protein hydrolysates, which are useful flavour enhancers. These chlorinated steroids may also attract attention as environmental contaminants if they are released from liquid crystal display
N Weber
Food and chemical toxicology : an international journal published for the British Industrial Biological Research Association, 27(4), 259-263 (1989-04-01)
A method for the analysis of 3 beta-chloro steroids by high-performance liquid chromatography is described. These compounds are known to occur in commercial protein hydrolysates. The gastro-intestinal absorption, distribution and metabolism of chlorinated steroids were studied after their intragastric application
Kamlesh Sharma et al.
Journal of molecular modeling, 11(2), 135-140 (2005-04-20)
This work describes a theoretical approach to the substitution reaction mechanism involving the conversion of cholesterol to cholesteryl chloride. Two chlorosulfite ester molecules were formed as intermediates. An iso-steroid was found as the transition state. The final product was cholesteryl
Smiljka S Milisavljević et al.
Steroids, 70(13), 867-872 (2005-07-26)
Four 5,6-unsaturated steroids--3beta-chlorocholest-5-ene (1a), cholesterol (1b) and its acetate (1c) and benzoate (1d)-were subjected to constant current electrolysis (50 mA, 2 F mol(-1)) in an electrolytic cell divided by a ceramic membrane, using a platinum foil as the anode and

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