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647640

Sigma-Aldrich

Zirconium(IV) chloride

anhydrous, powder, 99.99% trace metals basis

Sinonimo/i:

Tetrachlorozirconium, Zirconium tetrachloride

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5 G
130,00 €
25 G
520,00 €

130,00 €

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Cambia visualizzazione
5 G
130,00 €
25 G
520,00 €

About This Item

Formula condensata:
ZrCl4
Numero CAS:
10026-11-6
Peso molecolare:
233.04
Numero CE:
233-058-2
Numero MDL:
MFCD00011306
Codice UNSPSC:
12352302
ID PubChem:
24883414
NACRES:
NA.23

130,00 €

Per informazioni sulla disponibilità, contatta il Servizio Clienti.
Richiedi un ordine bulk

Grado

anhydrous

Livello qualitativo

100

Tensione di vapore

1 mmHg ( 190 °C)

Saggio

99.99% trace metals basis

Stato

powder

Impiego in reazioni chimiche

reagent type: catalyst
core: zirconium

Impurezze

<50 ppm hafnium

Temp. transizione

sublimation point 331 °C

Densità

2.8 g/mL at 25 °C (lit.)

applicazioni

battery manufacturing

Stringa SMILE

Cl[Zr](Cl)(Cl)Cl

InChI

1S/4ClH.Zr/h4*1H;/q;;;;+4/p-4
DUNKXUFBGCUVQW-UHFFFAOYSA-J

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Categorie correlate

Descrizione generale

Zirconium(IV) chloride (ZrCl4) is a Lewis acid catalyst, which has low toxicity. It is a moisture resistant material that is used as a catalyst in organic transformations.[1]

Applicazioni

ZrCl4 can be used as a catalyst for a variety of organic syntheses, such as Friedel-Crafts reaction, condensation reaction and other reduction reactions.[2]

Accessorio

N° Catalogo
Descrizione
Determinazione del prezzo

Pittogrammi

Corrosion
GHS05

Avvertenze

Danger

Indicazioni di pericolo

H290,H314

Classi di pericolo

Met. Corr. 1 - Skin Corr. 1B

Rischi supp

EUH014,EUH071

Codice della classe di stoccaggio

8B - Non-combustible corrosive hazardous materials

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificati d'analisi (COA)

Lot/Batch Number
0000411955
0000411955
0000406810
0000282375
0000282375

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Erik A Wu et al.
Nature communications, 12(1), 1256-1256 (2021-02-25)
Rechargeable solid-state sodium-ion batteries (SSSBs) hold great promise for safer and more energy-dense energy storage. However, the poor electrochemical stability between current sulfide-based solid electrolytes and high-voltage oxide cathodes has limited their long-term cycling performance and practicality. Here, we report
Synthesis of 2, 3-dihydroquinazolin-4 (1H)-ones catalyzed by zirconium (IV) chloride as a mild and efficient catalyst
Abdollahi-Alibeik M and Shabani E
Chinese Chemical Letters = Zhongguo Hua Xue Kuai Bao, 22(10), 1163-1166 (2011)
Applications of zirconium (IV) chloride in organic synthesis
Smitha G, et al.
Synthesis, 2008(06), 829-855 (2008)
Harish Kumar et al.
Ultrasonics sonochemistry, 15(2), 129-132 (2007-04-17)
Sonication of aromatic aldehydes, urea and ethyl acetoacetate in presence of solvent (ethyl alcohol) or solvent-less dry media (bentonite clay) supported-zirconium (IV) chloride (ZrCl(4)) as catalyst at 35 kHz gives 6-methyl-4-substitutedphenyl-2-oxo-1,2,3,4-tetrahydropyrimidine-5-carboxylic acid ethyl esters proficiently in high yields.
Ilanit Doron-Mor et al.
Langmuir : the ACS journal of surfaces and colloids, 20(24), 10727-10733 (2004-11-17)
Coordination self-assembly of bishydroxamate-based metal-organic multilayers on gold employing a layer-by-layer (LbL) approach was investigated. It is shown that the solution chemistry of the participating metal ion has a marked influence on the composition and properties of the multilayers. Use
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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 risposta

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 risposta

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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