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320129

Sigma-Aldrich

Acetyl chloride

reagent grade, 98%

Sinonimo/i:

Acetic acid chloride, Acetic chloride, Ethanoyl chloride

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1 KG
128,00 €

128,00 €

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1 KG
128,00 €

About This Item

Formula condensata:
CH3COCl
Numero CAS:
75-36-5
Peso molecolare:
78.50
Beilstein:
605303
Numero CE:
200-865-6
Numero MDL:
MFCD00000719
Codice UNSPSC:
12352100
ID PubChem:
24859250
NACRES:
NA.22
Stato:
liquid
Saggio:
98%

128,00 €

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Richiedi un ordine bulk

Grado

reagent grade

Livello qualitativo

200

Densità del vapore

2.7 (vs air)

Tensione di vapore

11.69 psi ( 20 °C)
32.33 psi ( 55 °C)

Saggio

98%

Stato

liquid

Temp. autoaccensione

1353 °F

Limite di esplosione

19 %

Indice di rifrazione

n20/D 1.389 (lit.)

P. ebollizione

52 °C (lit.)

Punto di fusione

−112 °C (lit.)

Densità

1.104 g/mL at 25 °C (lit.)

Gruppo funzionale

acyl chloride

Stringa SMILE

CC(Cl)=O

InChI

1S/C2H3ClO/c1-2(3)4/h1H3
WETWJCDKMRHUPV-UHFFFAOYSA-N

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Descrizione generale

Acetyl chloride undergoes reaction with decalin and aluminum trichloride to afford a tricyclic enol ether.[1] It promotes the cyclopropanation of alkene with dibromomethane or diiodomethane in the presence of Zn dust and copper chloride in ether.[2] Friedel-Crafts reaction of acetyl chloride with benzene in the presence of MCl3 (M = Al or Fe) in the ionic liquid 1-butyl-3-methylimidazolium chloride affords MCl3 adducts of the acetyl chloride, the acetylium ion [CH3CO]+[MCl4]- and the MCl3 adduct of acetophenone.[3]

Applicazioni

  • Synthesis, Characterization, and Evaluation of Thiazolidine Derivatives of Cysteine for Suppressing Eumelanin Production.: The study discusses the synthesis and evaluation of thiazolidine derivatives of cysteine, where acetyl chloride is used as a reagent, underscoring its importance in pharmaceutical intermediate development. (Amino et al., 2016).
  • New URJC-1 Material with Remarkable Stability and Acid-Base Catalytic Properties.: This research introduces the new URJC-1 material, noting its stability and catalytic properties, with acetyl chloride being pivotal in the synthesis process, illustrating its role in material science and catalysis. (Leo et al., 2016).

Pittogrammi

FlameCorrosion
GHS02,GHS05

Avvertenze

Danger

Indicazioni di pericolo

H225,H314

Classi di pericolo

Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B

Rischi supp

EUH014

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 1

Punto d’infiammabilità (°F)

41.0 °F - closed cup

Punto d’infiammabilità (°C)

5 °C - closed cup

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Certificati d'analisi (COA)

Lot/Batch Number
SDBB0881
STBL4167
STBL4166
SDBB1861
MKCV7127

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Acetyl chloride-d3 99 atom % D

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Chloroacetyl chloride 98%

Sigma-Aldrich

104493

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Benzoil cloruro 99%

Sigma-Aldrich

259950

Benzoil cloruro

Isobutyryl chloride 98%

Sigma-Aldrich

139122

Isobutyryl chloride

Thionyl chloride reagent grade, 97%

Sigma-Aldrich

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Sigma-Aldrich

D55008

Dichloroacetyl chloride

Acetyl chloride promoted cyclopropanations of alkenes with dibromomethane using zinc dust and copper (I) chloride in ether.
Friedrich EC and Lewis EJ.
The Journal of Organic Chemistry, 55(8), 2491-2494 (1990)
In situ infrared spectroscopic studies of the Friedel-Crafts acetylation of benzene in ionic liquids using AlCl3 and FeCl3.
Csihony S, et al.
Green Chemistry, 3(6), 307-309 (2001)
Catherine L Lyall et al.
Journal of the American Chemical Society, 136(39), 13745-13753 (2014-09-10)
Decalin undergoes reaction with aluminum trichloride and acetyl chloride to form a tricyclic enol ether in good yield, as first reported by Baddeley. This eye-catching transformation, which may be considered to be an aliphatic Friedel-Crafts reaction, has not previously been
Facile catalyzed acylation of alcohols, phenols, amines and thiols based on ZrOCl 2? 8H 2 O and acetyl chloride in solution and in solvent-free conditions.
Ghosh R, et al.
Tetrahedron Letters, 46(1), 147-151 (2005)
Oxetanes. VII. Synthesis from 1, 3-Diols. Reactions of Oxetanes and of 1, 3-Butanediol with Hydrogen Chloride, Hydrogen Bromide and Acetyl Chloride1, 2.
Searles JS, et al.
Journal of the American Chemical Society, 79(4), 952-956 (1957)
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Articoli

Friedel–Crafts Acylation

Friedel-Crafts acylation with Lewis acid catalysts forms monoacylated products via electrophilic aromatic substitution of arenes.

Domande

1–3 di 3 domande  

  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 risposta

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 risposta

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  3. Is this chemical react with eppendorf tubes? Especially when heated?

    1 risposta

    1. The most stable materials for use with Acetyl Chloride are FEP and PVDF. Fluoroethylenepropylene (FEP) is not recommended for high heat conditions. While the product number has not been provided, most Eppendorf tubes are polypropylene. Polypropylene is not compatible with this Acetyl Chloride.

      Further information may be available from our Technical Service team who can assist you further. We kindly ask you to navigate to the link https://www.sigmaaldrich.com/techservice, click on "Product Technical Inquires" under the Products Section with all the required information so that a member of our team can reach out to you to assist further. Thank you.

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