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Sigma-Aldrich

Methyl trifluoromethanesulfonate

≥98%

Sinonimo/i:

Methyl triflate

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10 G
78,00 €
50 G
280,00 €
250 G
382,50 €

78,00 €


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10 G
78,00 €
50 G
280,00 €
250 G
382,50 €

About This Item

Formula condensata:
CF3SO2OCH3
Numero CAS:
Peso molecolare:
164.10
Beilstein:
774772
Numero CE:
Numero MDL:
Codice UNSPSC:
12352108
ID PubChem:
NACRES:
NA.22

78,00 €


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Livello qualitativo

Saggio

≥98%

Stato

liquid

Indice di rifrazione

n20/D 1.326 (lit.)

P. ebollizione

94-99 °C (lit.)

Densità

1.45 g/mL at 25 °C (lit.)

Gruppo funzionale

fluoro
triflate

Temperatura di conservazione

2-8°C

Stringa SMILE

COS(=O)(=O)C(F)(F)F

InChI

1S/C2H3F3O3S/c1-8-9(6,7)2(3,4)5/h1H3
OIRDBPQYVWXNSJ-UHFFFAOYSA-N

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Categorie correlate

Descrizione generale

Methyl trifluoromethanesulfonate is a strong methylating reagent,[1] commonly used for the pre-methylation of polysaccharides under mild basic conditions.[2]

Applicazioni

Methyl trifluoromethanesulfonate can be used as a methylation reagent:
  • In the determination of polysulfides, zerovalent sulfur in sulfide-rich water wells,[3] and polysulfide species in electrolyte of a lithium–sulfur battery[4] using chromatography-based techniques.
  • In reactions with potassium enolates.[5]
  • For the conversion of amines to methyl ammonium triflates.[6][7]

Accessorio

N° Catalogo
Descrizione
Determinazione del prezzo

Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Acute Tox. 1 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

100.4 °F - closed cup

Punto d’infiammabilità (°C)

38 °C - closed cup

Dispositivi di protezione individuale

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Certificati d'analisi (COA)

Lot/Batch Number

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Speciation of polysulfides and zerovalent sulfur in sulfide-rich water wells in southern and central Israel
Kamyshny A, et al.
Aquatic Geochemistry, 14(2), 171-192 (2008)
Purification of Laboratory Chemicals, 6 (2009)
Analytical Methods in Wood Chemistry, Pulping, and Papermaking (1998)
Ring Expansions of 2-Alkenylazetidinium Salts-a New Route to Pyrrolidines and Azepanes
Couty F, et al.
European Journal of Organic Chemistry, 2006(18), 4214-4223 (2006)
Quantitative and Qualitative Determination of Polysulfide Species in the Electrolyte of a Lithium?Sulfur Battery using HPLC ESI/MS with One?Step Derivatization
Zheng D, et al.
Advanced Energy Materials, 5(16) (2015)

Domande

1–2 di 2 domande  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 risposta
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Utile?

  2. How can I determine the shelf life / expiration / retest date of this product?

    1 risposta
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Utile?

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