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Method for activation and recycling of trityl resins.

The Journal of organic chemistry (2012-07-20)
Itedale Namro Redwan, Morten Grøtli
KIVONAT

This note describes a rapid and mild strategy for the loading of alcohols and anilines onto a polystyrene triphenylmethyl (trityl) resin. High loadings were obtained in a matter of minutes by treating resin-bound trityl chloride with triethyloxonium tetrafluoroborate followed by alcohols or anilines. Yields were comparable or better than known literature methods. Recycling of the recovered resin was also possible using the developed method.

ANYAGOK
Cikkszám
Márka
Termékleírás

Sigma-Aldrich
Triethyloxonium tetrafluoroborate, ≥97.0% (T)
Sigma-Aldrich
Triethyloxonium tetrafluoroborate solution, 1.0 M in methylene chloride
Sigma-Aldrich
Trityl chloride, purum, ≥97.0% (HPLC), ≥97.0% (AT)
Sigma-Aldrich
Trityl chloride, 97%