561657

(1,3-Dioxan-2-ylethyl)magnesium bromide solution

0.5 M in THF

• Synonyma: 1,3-Dioxane - 2-ethyl- magnesium complex, [2-(1,3-Dioxan-2-yl)ethyl]magnesium bromide
• Empirický vzorec (Hillův zápis): C₆H₁₁BrMgO₂
• Číslo CAS: 480438-44-6
• Molekulová hmotnost: 219.36
• NACRES: NA.22
• PubChem Substance ID: 24879959
• UNSPSC Code: 12352103
• MDL number: MFCD00061518

Vlastnosti

• reaction suitability: reaction type: Grignard Reaction
• Quality Segment: 100
• packaging: Sure/Seal^™ of
• concentration: 0.5 M in THF
• bp: 65 °C
• density: 0.951 g/mL at 25 °C
• functional group: ether
• storage temp.: 2-8°C
• SMILES string: Br[Mg]CCC1OCCCO1
• InChI: 1S/C6H11O2.BrH.Mg/c1-2-6-7-4-3-5-8-6;;/h6H,1-5H2;1H;/q;;+1/p-1
• InChI key: JYNXRXBIEHSSLR-UHFFFAOYSA-M

Popis

Application

(1,3-Dioxan-2-ylethyl)magnesium bromide can be used:

• In a Grignard addition-acylation method for the preparation of enamides.
• To prepare trisubstituted allenes by reacting with propargylic ammonium salts.
• In one of the key synthetic steps for the synthesis of febrifugine based antimalarial drugs.

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

Bezpečnostní informace

• Piktogramy: GHS02,GHS08,GHS05,GHS07
• Výstražné slovo: Danger
• Kódy nebezpečí: H225,H302,H318,H335,H336,H351
• Cílové orgány: Central nervous system, Respiratory system
• supp_hazards: EUH019
• Skladovací třída: 3 - Flammable liquids
• Bod vzplanutí (°F): No data available
• Bod vzplanutí (°C): No data available
• Bezpečnostní pokyny: P202 - P210 - P280 - P301 + P312 - P305 + P351 + P338 - P308 + P313
• Hazard Classifications: Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - STOT SE 3