177261

DPPF

97%

• Synonyma: 1,1′-Ferrocenediyl-bis(diphenylphosphine), dppf
• Empirický vzorec (Hillův zápis): C₃₄H₂₈FeP₂
• Číslo CAS: 12150-46-8
• Molekulová hmotnost: 554.38
• MDL number: MFCD00001422
• UNSPSC Code: 12350000
• PubChem Substance ID: 24850625
• NACRES: NA.22

Vlastnosti

• assay: 97%
• form: powder
• reaction suitability: reaction type: Cross Couplings; reagent type: ligand; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reagent type: ligand; reaction type: Carbonylations; reagent type: ligand; reaction type: Ene Reaction; reagent type: ligand; reaction type: Heck Reaction; reagent type: ligand; reaction type: Negishi Coupling; reagent type: ligand; reaction type: Sonogashira Coupling; reagent type: ligand; reaction type: Stille Coupling; reagent type: ligand; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand; reaction type: Tsuji-Trost Reaction
• greener alternative product characteristics: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp: 181-182 °C (dec.) (lit.)
• functional group: phosphine
• greener alternative category: Aligned,
• SMILES string: [Fe].[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.[CH]4[CH][CH][C]([CH]4)P(c5ccccc5)c6ccccc6
• InChI: 1S/2C17H14P.Fe/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;/h2*1-14H;
• InChI key: HPXNTHKXCYMIJL-UHFFFAOYSA-N

Popis

General description

Novel functionalized furan derivatives were prepared via Pd-phosphine sequential C-C and C-O bond formation.

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Application

Ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing.

Ruthenium-Catalyzed N-Alkylation of Amines and Sulfonamides Using Borrowing Hydrogen Methodology

Ligand used in a Pd(II)-catalyzed cross-coupling synthesis of oxazepine ring systems.

Bezpečnostní informace

• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Gloves, type N95 (US)