567159

1,1′-Bis(phenylphosphinidene)ferrocene

97%, solid

• Synonyma: 1,1′-(Ferrocenediyl)phenylphosphine
• Lineární vzorec: C₅H₄PC₆H₅C₅H₄Fe
• Číslo CAS: 72954-06-4
• Molekulová hmotnost: 292.09
• UNSPSC Code: 12352005
• PubChem Substance ID: 24880349
• NACRES: NA.22
• MDL number: MFCD04974069

Vlastnosti

• Název produktu: 1,1′-Bis(phenylphosphinidene)ferrocene, 97%
• Quality Segment: 100
• assay: 97%
• form: solid
• reaction suitability: reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
• greener alternative product characteristics: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp: 88-92 °C (lit.)
• functional group: phosphine
• greener alternative category: Aligned
• storage temp.: 2-8°C
• SMILES string: [Fe].[CH]1[CH][CH][C]([CH]1)P([C]2[CH][CH][CH][CH]2)c3ccccc3
• InChI: 1S/C16H13P.Fe/c1-2-8-14(9-3-1)17(15-10-4-5-11-15)16-12-6-7-13-16;/h1-13H;
• InChI key: HKOUDNXXOXEYNZ-UHFFFAOYSA-N

Popis

General description

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. Ferrocene phosphine ligands are used as catalytic components in asymmetric hydrogenation reactions, enabling efficient and selective synthesis of chiral compounds, offering a greener, potentially more sustainable option for pharmaceutical manufacturing. Click here for more information.

Application

Reactant for:

• Preparation of macrocyclic tridentate ferrocenylphosphine ligands
• Preparation of phosphorus-bridged ferrocenophane with syn and anti conformations
• Reaction with phenyllithium and chlorophosphine to give ferrocenediyl ligand and its rhodium complex catalyst for selective hydroformylation of alkenes
• Ring-opening reactions via ring slippage
• Preparation of palladium chloro (ferrocene-bridged)phosphine-phosphonite complex for catalysis of Heck reaction of iodobenzene with Me acrylate

Bezpečnostní informace

• Skladovací třída: 11 - Combustible Solids
• wgk: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Gloves, type N95 (US)