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291056

Sigma-Aldrich

Methyl formate

anhydrous, 99%

Sinonimo/i:

Formic acid methyl ester

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About This Item

Formula condensata:
HCO2CH3
Numero CAS:
Peso molecolare:
60.05
Beilstein:
1734623
Numero CE:
Numero MDL:
Codice UNSPSC:
12352108
ID PubChem:
NACRES:
NA.21
Prezzi e disponibilità al momento non sono disponibili

Grado

anhydrous

Livello qualitativo

Densità del vapore

2.1 (vs air)

Tensione di vapore

32.91 psi ( 55 °C)
9.47 psi ( 20 °C)

Saggio

99%

Stato

liquid

Temp. autoaccensione

842 °F

Limite di esplosione

23 %

Impurezze

<0.005% water

Residuo dopo evaporazione

<0.0005%

Indice di rifrazione

n20/D 1.343 (lit.)

pH

4-5 (20 °C, 200 g/L)

P. ebollizione

32-34 °C (lit.)

Punto di fusione

−100 °C (lit.)

Densità

0.974 g/mL at 20 °C (lit.)

Stringa SMILE

[H]C(=O)OC

InChI

1S/C2H4O2/c1-4-2-3/h2H,1H3
TZIHFWKZFHZASV-UHFFFAOYSA-N

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Applicazioni

Methyl formate may be used in the synthesis of the following building blocks:
  • methyl 4-chloro-2-formylbutanoate from methyl 4-chlorobutanoate via [1]-formylation[1]
  • potassium methyl α-[(methoxyethylidene)amino]-β-hydroxyacrylate from methyl α-[(methoxyethylidene)amino]acetate[2]
  • (S)-(-)-1-formyl-2-hydroxymethylpyrrolidine from (S)-(+)-2-hydroxymethylpyrrolidine via N-formylation[3]

Avvertenze

Danger

Classi di pericolo

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Liq. 1 - STOT SE 1 - STOT SE 3

Organi bersaglio

Respiratory system

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 2

Punto d’infiammabilità (°F)

-2.2 °F - closed cup

Punto d’infiammabilità (°C)

-19 °C - closed cup

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves


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Certificati d'analisi (COA)

Lot/Batch Number

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I clienti hanno visto anche

Slide 1 of 9

1 of 9

4-Methoxycarbonyl-2-methyl-1,3-oxazole
White JD, et al
Organic Syntheses, 79, 244-244 (2002)
(S)-(-)-1-Amino-2-Methoxymethylpyrrolidine (SAMP) and (R)-(+)-1-Amino-2-Methoxymethylpyrrolidine (RAMP), Versatile Chiral Auxiliaries
Enders D, et al.
Organic Syntheses, 65, 173-173 (1987)
Barriers to rotation adjacent to double bonds. 3. The carbon-oxygen barrier in formic acid, methyl formate, acetic acid, and methyl acetate. The origin of ester and amide resonance.
Wiberg KB and Laidig KE.
Journal of the American Chemical Society, 109(20), 5935-5943 (1987)
Methyl formate as a carbonylating agent for the catalytic conversion of phenol to methyl phenyl carbonate.
Wu C, et al.
Green Chemistry, 17(3), 1467-1472 (2015)
Methyl N-Phenyl Carbamate Synthesis from Aniline and Methyl Formate: Carbon Recycling to Chemical Products.
Yalfani MS, et al.
ChemSusChem, 8(3), 443-447 (2015)

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

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