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77081

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α-Cyano-4-fluorocinnamic acid

matrix substance for MALDI-MS, ≥95.0% (HPLC)

Synonyme(s) :

α-Cyano-p-fluorocinnamic acid, 2-Cyano-3-(4-fluorophenyl)-2-propenoic acid, FCCA, NSC 638135

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About This Item

Formule empirique (notation de Hill):
C10H6FNO2
Numéro CAS:
118409-66-8
Poids moléculaire :
191.16
Numéro Beilstein :
10339054
Numéro MDL:
MFCD00466853
Code UNSPSC :
12000000
ID de substance PubChem :
329767465
Nomenclature NACRES :
NA.21

Qualité

matrix substance for MALDI-MS

Niveau de qualité

100

Pureté

≥95.0% (HPLC)

Forme

crystals

Classe(s) fonctionnelle(s) de l'analyte

drugs of abuse, ionic liquids (quantification)

Classe(s) chimique(s) de l'analyte

chlorinated lipids, lipids, peptides, phospholipids, phosphopeptides

Technique(s)

collision-induced dissociation MS/MS (CID-MS/MS): suitable
matrix-enhanced secondary ion MS (ME-SIMS): suitable

Solubilité

methanol: 100 mg/10 mL, clear, colorless to light yellow

Chaîne SMILES 

OC(/C(C#N)=C/C1=CC=C(F)C=C1)=O

InChI

1S/C10H6FNO2/c11-9-3-1-7(2-4-9)5-8(6-12)10(13)14/h1-5H,(H,13,14)/b8-5+

Clé InChI

OBZAFMILNGLRAL-VMPITWQZSA-N

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Application

suitable as MALDI-Matrix material

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Description
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MSCAL1

ProteoMass™ Peptide and Protein MALDI-MS Calibration Kit, Peptide and Protein MALDI MS Calibration Standard

MSCAL2

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2′,4′,6′-Trihydroxyacetophenone monohydrate, matrix substance for MALDI-MS, ≥99.5%

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trans-2-[3-(4-tert-Butylphenyl)-2-methyl-2-propenylidene]malononitrile, matrix substance for MALDI-MS, ≥99.0% (HPLC)

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2,5-Dihydroxybenzoic acid, matrix substance for MALDI-MS, >99.0% (HPLC)

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39319

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4-Chloro-α-cyanocinnamic acid, matrix substance for MALDI-MS, ≥95.0% (HPLC)

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PFS22

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Bruker standard solvent, suitable for MALDI-MS, 50% ACN + 47.5% H2O + 2.5% TFA

Pictogrammes

Exclamation mark
GHS07

Mention d'avertissement

Warning

Classification des risques

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Organes cibles

Respiratory system

Code de la classe de stockage

11 - Combustible Solids

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Choose from one of the most recent versions:

Certificats d'analyse (COA)

Lot/Batch Number
BCBL7696V
BCBL7696

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Retrouvez la documentation relative aux produits que vous avez récemment achetés dans la Bibliothèque de documents.

Consulter la Bibliothèque de documents

Dimitrios G Papasotiriou et al.
Journal of proteome research, 9(5), 2619-2629 (2010-04-07)
Peptide Mass Fingerprinting (PMF) of tryptically in-gel digested samples is a well-established protein identification technique for MALDI mass spectrometry but an in-depth PMF evaluation for in-gel digestions of less specific enzymes is still missing. This study demonstrates that the MALDI-LTQ-Orbitrap
Thorsten Jaskolla et al.
Journal of the American Society for Mass Spectrometry, 20(5), 867-874 (2009-02-10)
Phosphatidylethanolamines (PEs) are abundant lipid constituents of the cellular membrane. The amino group of PEs exhibits high reactivity with hypochlorous acid that is generated under inflammatory conditions in vivo. The analysis of the resulting PE mono- and dichloramines is of
Marcel Wiegelmann et al.
Analytical and bioanalytical chemistry, 405(22), 6925-6932 (2012-10-16)
A high analytical sensitivity in ultraviolet matrix-assisted laser desorption ionization mass spectrometry (MALDI-MS) is only achieved if the laser wavelength corresponds to a high optical absorption of the matrix. Laser fluence and the physicochemical properties of the compounds, e.g., the
Thorsten W Jaskolla et al.
Journal of proteome research, 8(7), 3588-3597 (2009-05-14)
The performance of the recently developed 4-chloro-alpha-cyanocinnamic acid (Cl-CCA) matrix-assisted laser desorption ionization mass spectrometry (MALDI MS) matrix was investigated in comparison to the most widely used matrix alpha-cyano-4-hydroxycinnamic acid (CHCA). For this purpose, in-solution digestions of standard proteins in
Jens Soltwisch et al.
Journal of the American Society for Mass Spectrometry, 24(10), 1477-1488 (2013-08-15)
The success of matrix-assisted laser desorption/ionization mass spectrometry (MALDI-MS) as a widely employed analytical tool in the biomolecular sciences builds strongly on an effective laser-material interaction that is resulting in a soft co-desorption and ionization of matrix and imbedded biomolecules.
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