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Merck

R4126

Sigma-Aldrich

Reinecke-Salz

Synonym(e):

Ammonium-tetrarhodanato-diamminchromat(III), Ammonium-tetrathiocyanato-diammin-chromat(III), Ammonium-tetrathiocyanodiammonochromat, Ammoniumreineckat

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About This Item

Lineare Formel:
NH4[Cr(NH3)2(SCN)4]
CAS-Nummer:
Molekulargewicht:
336.43
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352302
PubChem Substanz-ID:
NACRES:
NA.21

Form

powder

mp (Schmelzpunkt)

268-272 °C (dec.) (lit.)

SMILES String

N.N.[NH4+].N#CS[Cr-](SC#N)(SC#N)SC#N

InChI

1S/4CHNS.Cr.3H3N/c4*2-1-3;;;;/h4*3H;;3*1H3/q;;;;+3;;;/p-3

InChIKey

ZGLIQORZYPZFPW-UHFFFAOYSA-K

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Anwendung

Reinecke salt can be used as a precipitation reagent for the precipitation of basic compounds such as amines, amino acids, and alkaloids as their reineckate complexes. It is also used in the spectrophotometric determination of promazine along with alizarin S by the formation of the promazine ion-association complex.

Piktogramme

Exclamation mark

Signalwort

Warning

Gefahreneinstufungen

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral

Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable


Analysenzertifikate (COA)

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Die Dokumentenbibliothek aufrufen

Preparation of histones by the use of Reinecke salt.
Lindh NO and Brantmark BL.
Analytical Biochemistry, 10(3), 415-420 (1965)
L Campanella et al.
Journal of pharmaceutical and biomedical analysis, 14(8-10), 1047-1054 (1996-06-01)
A new cocaine-sensitive ISFET device based on a cocaine-reineckate ion-pair complex dispersed in a PVC--sebacate matrix has been fabricated. this sensor displays a linear range for cocaine hydrochloride between about 3 x 10(-6) and 2 x 10(-2) M and a
M F el-Shahat et al.
Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986), 54(2), 175-181 (1992-01-01)
A spectrophotometric method for the determination of some alkaloids (namely ephedrine HCl, cinchonine HCl, chlorpheniramine maleate, atropine sulphate and diphenhydramine HCl) as separate compounds as well as in pharmaceutical preparations through the formation of their ion-pair (reineckate complexes) is described.
Sheikha M Al-Ghannam
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 69(4), 1188-1194 (2007-08-11)
Three accurate, rapid and simple atomic absorption spectrometric (AAS), conductometric and colorimetric methods were developed for the determination of gatifloxacin (GTF), moxifloxacin (MXF) and sparfloxacin (SPF). The proposed methods depend upon the reaction of ammonium reineckate with the studied drugs
M Eisman et al.
Journal of pharmaceutical and biomedical analysis, 11(4-5), 301-305 (1993-04-01)
An automatic method for the determination of amylocaine and bromhexine hydrochloride by atomic absorption spectrometry (AAS) is proposed. The drugs were determined indirectly by formation of reineckates, extraction into 1,2-dichloroethane and measurement of chromium in the organic phase. The chemical

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