701475

Dichlor-[(2,6,10-dodecatrien)-1,12-diyl]ruthenium(IV)

• Synonym(e): Dichloro-(dodeca-2,6,10-trien-1,12-diyl)-ruthenium(IV), Dichloro-2,6,10-dodecatrienylen-ruthenium, Dichloro-[(1,2,3,6,7,10,11,12-η)-2,6,10-dodecatrien-1,12-diyl]-ruthenium
• Empirische Formel (Hill-System): C₁₂H₁₈Cl₂Ru
• CAS-Nummer: 12170-97-7
• Molekulargewicht: 334.25
• MDL-Nummer: MFCD08459354
• UNSPSC-Code: 12161600
• PubChem Substanz-ID: 329762293
• NACRES: NA.22

Eigenschaften

• Form: powder
• Eignung der Reaktion: core: ruthenium; reagent type: catalyst
• mp (Schmelzpunkt): 190 °C
• SMILES String: Cl[Ru]1(Cl)C\C=C\CCC=CCC\C=C\C1
• InChI: 1S/C12H18.2ClH.Ru/c1-3-5-7-9-11-12-10-8-6-4-2;;;/h3-6,11-12H,1-2,7-10H2;2*1H;/q;;;+2/p-2/b5-3+,6-4+,12-11-;;;
• InChIKey: RSRAKQPWMXANGM-LXALEWKWSA-L

Beschreibung

Anwendung

Catalyst for:

• Redox isomerization/transfer hydrogenation
• Deprotection of N-allyl amides and lactams
• Isomerization of allylamines
• Isomerization of allylic alcohols into carbonyl compounds

Catalysts used in the deprotection of N-allyl amides and lactams

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H335
• P-Sätze: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: dust mask type N95 (US), Eyeshields, Gloves