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440167

Sigma-Aldrich

(3-Glycidyloxypropyl)trimethoxysilan

≥98%

Synonym(e):

Dow Corning® Produkt Z-6040, 3-(2,3-Epoxypropoxy)propyltrimethoxysilan, GLYMO, Glycidyl-3-(trimethoxysilyl)-propylether

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100 ML
CHF 69.20
500 ML
CHF 305.00
1 L
CHF 633.00
2.5 L
CHF 1’450.00

CHF 69.20

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100 ML
CHF 69.20
500 ML
CHF 305.00
1 L
CHF 633.00
2.5 L
CHF 1’450.00

About This Item

Empirische Formel (Hill-System):
C9H20O5Si
CAS-Nummer:
2530-83-8
Molekulargewicht:
236.34
Beilstein:
4308125
EG-Nummer:
219-784-2
MDL-Nummer:
MFCD00005144
UNSPSC-Code:
12352103
PubChem Substanz-ID:
24867573
NACRES:
NA.23

CHF 69.20

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Qualitätsniveau

200

Assay

≥98%

Form

liquid

Brechungsindex

n20/D 1.429 (lit.)

bp

120 °C/2 mmHg (lit.)

Dichte

1.07 g/mL at 25 °C (lit.)

SMILES String

CO[Si](CCCOCC1CO1)(OC)OC

InChI

1S/C9H20O5Si/c1-10-15(11-2,12-3)6-4-5-13-7-9-8-14-9/h9H,4-8H2,1-3H3

InChIKey

BPSIOYPQMFLKFR-UHFFFAOYSA-N

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Verwandte Kategorien

Allgemeine Beschreibung

3-Glycidoxypropyltrimethoxysilan (GPTMS) ist ein bifunktionelles Organsilan mit drei Methoxygruppen auf einer Seite und einem Epoxidring auf der anderen. Die Methoxygruppen binden gut mit Glassubstraten und erzeugen eine 3D-Matrix. Die Epoxidgruppe reagiert mit Amiden, Alkoholen, Thiolen und Säuren. GPTMS ist hoch reaktiv in Wasser und kann als Vernetzer zwischen der Kieselsäureoberfläche und der Polymermatrix eingesetzt werden.[1][2][3]

Anwendung

Eine Vorbehandlung von Kohlenstoffstahl mit 3-Glycidoxypropyltrimethoxysilan verbessert die Trocken- und Nassadhäsion und reduziert gleichzeitig die kathodische Enthaftungsrate einer Epoxidbeschichtung.[4]
GPTMS wird häufig als Kieselsäurevorläufer eingesetzt. GPTMS allein mit Tetraethylortosilikat (TEOS) kann mit Chitosan vermischt und als Füllmaterial für Polymergerüste Knochengewebezüchtung verwendet werden.[5] Es kann auch zur Beschichtung von Aluminiumlegierung als Korrosionsschutz verwendet werden.[6] GPTMS kann zur Funktionalisierung (Umwicklung) mehrwandiger Kohlenstoff-Nanoröhrchen (MWCNT) zur Verstärkung in Expoidmatrix-Nanokompositen eingesetzt werden.[2]

Piktogramme

Corrosion
GHS05

Signalwort

Danger

H-Sätze

H318,H412

Gefahreneinstufungen

Aquatic Chronic 3 - Eye Dam. 1

Lagerklassenschlüssel

10 - Combustible liquids

WGK

WGK 1

Flammpunkt (°F)

235.4 °F - closed cup

Flammpunkt (°C)

113 °C - closed cup

Persönliche Schutzausrüstung

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

Hier finden Sie alle aktuellen Versionen:

Analysenzertifikate (COA)

Lot/Batch Number
SDBB1794
SDBB1793
SDBB0475
STBL0642
STBL2731

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In der Dokumentenbibliothek finden Sie die Dokumentation zu den Produkten, die Sie kürzlich erworben haben.

Die Dokumentenbibliothek aufrufen

Functionalization of carbon nanotubes with (3-glycidyloxypropyl)-trimethoxysilane: Effect of wrapping on epoxy matrix nanocomposites.
Hoepfner, et al.
Journal of Applied Polymer Science, 133(47), 814-820 (2016)
Jadra Mosa et al.
Membranes, 9(9) (2019-08-30)
Organic/inorganic hybrid membranes that are based on GTT (GPTMS-TMES-TPTE) system while using 3-Glycidoxypropyl-trimethoxysilane (GPTMS), Trimethyletoxisilane (TMES), and Trimethylolpropane triglycidyl ether (TPTE) as precursors have been obtained while using a combination of organic polymerization and sol-gel synthesis to be used as
Journal of the Chemical Society. Perkin Transactions 1, 729-729 (1997)
Journal of Organometallic Chemistry, 625, 208-208 (2001)
Harun, M.K.; et al.
Progress in Organic Coatings, 4, 317-317 (2005)
Alle zugehörigen Dokumente anzeigen

Artikel

Synthesis of Melting Gels Using Mono-Substituted and Di-Substituted Alkoxysiloxanes

Synthesis of Melting Gels Using Mono-Substituted and Di-Substituted Alkoxysiloxanes

Questions

1–9 of 9 Questions  

  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  3. I would like to know the solvent for GPTMS. What solvents does GPTMS dispersed in?

    1 answer

    1. This product is supplied as a neat or pure liquid with a density of 1.07 g/mL. The minimum purity is 98%. This compound is soluble in water, alcohols, acetone, and most aliphatic esters at normal application levels of 45%.

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  4. I connected  GPTMS synthetically to my lipid(APTES), now my lipid cannot be dissolved in chloroform, ethanol and methanol solutions, which was previously dissolved, what solvent should I use?

    1 answer

    1. The solubility of the GPTMS/APTES sample has not been tested, however decreasing the concentration in chloroform may be useful. Other solvents such as oils (see C8267) or a strong base, such as sodium hydroxide, may also be an option. See the link below to a publication that may be of interest:
      https://pubs.acs.org/doi/10.1021/acssuschemeng.9b06741

      If you have any further issues, please contact https://www.sigmaaldrich.com/techservice, click on "Product Technical Inquiries" under the Products Section, and provide the required information so that a member of the Technical Service team can reach out to assist further. Thank you.

      Helpful?

  5. What is the Department of Transportation shipping information for this product?

    1 answer

    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

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  6. What is the viscosity of Product 440167 (3-Glycidyloxypropyl)trimethoxysilane GLYMO?

    1 answer

    1. This material is a low viscosity liquid with an average value of about 3 centistokes. Please note that this value is not part of our specifications.

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  7. Is Product 440167 (3-Glycidyloxypropyl)trimethoxysilane GLYMO, equivalent to Dow's Z-6040?

    1 answer

    1. Yes. This listing is manufactured by Dow Corning Corporation and distributed by Sigma-Aldrich.

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  8. What can Product 440167, 3-Glycidyloxypropyl)trimethoxysilane GLYMO, be used for?

    1 answer

    1. According to Dow Corning®, 3-GLYCIDOXYPROPYLTRIMETHOXYSILANE can be used as a coupling agent for many thermoset resins with glass or  mineral fillers. Specifically, it has been used as a reinforcement treatment on glass fiber to improve physical properties (especially wet strength) or as  an adhesion promoter to improve the bonding of a polymer coating or adhesive to glass, metals or other polymeric surfaces.

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  9. Where can I find more detailed information about how to use Product 440167. 3-Glycidyloxypropyl)trimethoxysilane, GLYMO, in adhesion/reinforcement applications?

    1 answer

    1. Dow Corning® has published a technical bulletin on this product, which is available by calling Technical Service at 800-231-8327.

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