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175617

Sigma-Aldrich

(3-Mercaptopropyl)trimethoxysilan

95%

Synonym(e):

3-(Trimethoxysilyl)-1-propanethiol

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25 G
CHF 53.00
100 G
CHF 164.00
500 G
CHF 585.00

About This Item

Lineare Formel:
HS(CH2)3Si(OCH3)3
CAS-Nummer:
Molekulargewicht:
196.34
Beilstein:
2038119
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352103
PubChem Substanz-ID:
NACRES:
NA.23

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Qualitätsniveau

Assay

95%

Form

liquid

Brechungsindex

n20/D 1.444 (lit.)

bp

213-215 °C (lit.)

Dichte

1.057 g/mL at 25 °C (lit.)

Lagertemp.

2-8°C

SMILES String

CO[Si](CCCS)(OC)OC

InChI

1S/C6H16O3SSi/c1-7-11(8-2,9-3)6-4-5-10/h10H,4-6H2,1-3H3

InChIKey

UUEWCQRISZBELL-UHFFFAOYSA-N

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Allgemeine Beschreibung

(3-Mercaptopropyl)trimethoxysilan (MPTMS) ist ein Organosilan mit einer Thiolgruppe, das als selbstorganisierende Monolage (Self-assembled Monolayer, SAM) verwendet werden kann. Es kann als Verbindungsreagenz zur Immobilisierung verschiedener Nanopartikel eingesetzt werden.[1][2]
(3-Mercaptopropyl)trimethoxysilan (MPTMS) wird vorherrschend als Vorstufe von Kieselerde verwendet.

Anwendung

MPTMS kann zum Schutz vor Korrosion auf quaternärer Bronze in urbaner Atmosphäre mit TiO2, CeO2 und La2O3 beschichtet werden.[3] Es kann außerdem als Kieselerde-Nanofluid (NF) verwendet werden, um die Oberfläche von Berea-Sandstein zu modifizieren und so den Bereich der tertiären Ölgewinnung (Enhanced Oil Recovery, EOR) in der Erdölindustrie zu verbessern.[1] MPTMS bildet ein Komposit mit Kaolin, das als Absorbens zur Entfernung von Schwermetallen aus Abwässern verwendet werden kann.[4] MPTMS kann eine Doppelschicht mit mehrwandigen Kohlenstoffnanoröhrchen (MWNT) auf Goldelektroden bilden, die zur Erforschung der elektrochemischen Eigenschaften von Fluphenazin verwendet werden können.[2]

Piktogramme

Exclamation markEnvironment

Signalwort

Warning

Gefahreneinstufungen

Acute Tox. 4 Oral - Aquatic Chronic 2 - Skin Sens. 1

Lagerklassenschlüssel

10 - Combustible liquids

WGK

WGK 2

Flammpunkt (°F)

204.8 °F - closed cup

Flammpunkt (°C)

96 °C - closed cup

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


Hier finden Sie alle aktuellen Versionen:

Analysenzertifikate (COA)

Lot/Batch Number

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In der Dokumentenbibliothek finden Sie die Dokumentation zu den Produkten, die Sie kürzlich erworben haben.

Die Dokumentenbibliothek aufrufen

Self-assembly of (3-mercaptopropyl) trimethoxysilane on polycrystalline zinc substrates towards corrosion protection
Sinapi F, et al.
Applied Surface Science, 212, 464-471 (2003)
Organosilane coatings applied on bronze: influence of UV radiation and thermal cycles on the protectiveness.
Chiavari C, et al.
Progress in Organic Coatings, 82(2), 91-100 (2015)
Baizhao Zeng et al.
Talanta, 64(2), 380-386 (2008-10-31)
A novel multi-walled carbon nanotubes/(3-mercaptopropyl)trimethoxysilane (MPS) bilayer modified gold electrode was prepared and used to study the electrochemcial behavior of fluphenazine and determine it. Fluphenazine could effectively accumulate at this electrode and produce two anodic peaks at about 0.78V and
P Knittel et al.
Faraday discussions, 193, 353-369 (2016-10-07)
The characterization of nanoparticles and the correlation of physical properties such as size and shape to their (electro)chemical properties is an emerging field, which may facilitate future optimization and tuning of devices involving nanoparticles. This requires the investigation of individual
Synthesis and luminescence of (3-mercaptopropyl)-trimethoxysilane capped CdS quantum dots
Wuister SF, et al.
Journal of Luminescence, 102, 338-343 (2003)

Questions

1–8 of 8 Questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  3. How to dissolve (3-mercaptopropyl)trimethoxysilane (MPTMS) solid into liquid?

    1 answer
    1. The solubility of this product has not been determined. However, various sources state that this material is soluble in water, ethanol, methanol, isopropanol, toluene, xylene, and benzene. No rate is provided. This information has not been validated.

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  4. If I stored it in room temperature, I couldn't use it anymore?

    1 answer
    1. The recommended storage temperature is 2-8°C. This product is shipped at ambient temperature. We typically allow one to two weeks transit time before we expect degradation for products shipped in this manner. For extended periods or unsealed products, the end-user should examine the material for suitability.

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  5. Is Product 175617, (3-Mercaptopropyl)trimethoxysilane, a liquid?

    1 answer
    1. Yes, 175617 is a liquid. The density is 1.057 g/mL at 25 °C(lit.). For example, the 25G package contains 23.7mL.

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  6. What is the purity of Product 175617, (3-Mercaptopropyl)trimethoxysilane?

    1 answer
    1. The purity is lot specific, but it will not be less than 94% as stated on the Specification Sheet.

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  7. What is the boiling point of Product 175617, (3-Mercaptopropyl)trimethoxysilane?

    1 answer
    1. The boiling point for this product is 213-215°C.

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  8. What is the Department of Transportation shipping information for this product?

    1 answer
    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

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