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Sigma-Aldrich

Triisobutylsilan

99%

Synonym(e):

Tris(2-methylpropyl)silane

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About This Item

Lineare Formel:
[(CH3)2CHCH2]3SiH
CAS-Nummer:
6485-81-0
Molekulargewicht:
200.44
Beilstein:
1738887
MDL-Nummer:
MFCD00010340
UNSPSC-Code:
12352103
PubChem Substanz-ID:
24856831
NACRES:
NA.22

Assay

99%

Brechungsindex

n20/D 1.435 (lit.)

bp

204-206 °C (lit.)

Dichte

0.764 g/mL at 25 °C (lit.)

SMILES String

CC(C)C[SiH](CC(C)C)CC(C)C

InChI

1S/C12H28Si/c1-10(2)7-13(8-11(3)4)9-12(5)6/h10-13H,7-9H2,1-6H3

InChIKey

BORQTRQJFUNMBC-UHFFFAOYSA-N

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Allgemeine Beschreibung

Triisobutylsilane (TIBS) is a versatile organosilicon compound that finds several applications in organic synthesis. Some of its common applications include desulfurization, deprotection of the N-boc group, and radical reactions.

Anwendung

Triisobutylsilane can be used as a reagent in combination with trifluoroacetic acid (TFA) for the deprotection of the Fmoc functional group.

Piktogramme

Exclamation mark
GHS07

Signalwort

Warning

Gefahreneinstufungen

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Zielorgane

Respiratory system

Lagerklassenschlüssel

10 - Combustible liquids

WGK

WGK 3

Flammpunkt (°F)

228.2 °F - closed cup

Flammpunkt (°C)

109 °C - closed cup

Persönliche Schutzausrüstung

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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