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Dokumente

115150

Sigma-Aldrich

Thiophosgen

Synonym(e):

Thiocarbonylchlorid

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About This Item

Lineare Formel:
CSCl2
CAS-Nummer:
463-71-8
Molekulargewicht:
114.98
Beilstein:
1633495
EG-Nummer:
207-341-6
MDL-Nummer:
MFCD00004918
UNSPSC-Code:
12352000
eCl@ss:
38020402
PubChem Substanz-ID:
24847201
NACRES:
NA.22

Dampfdichte

4 (vs air)

Qualitätsniveau

200

Eignung der Reaktion

reaction type: Carbonylations

Brechungsindex

n20/D 1.548 (lit.)

bp

70-75 °C (lit.)

Dichte

1.50 g/mL at 20 °C (lit.)

Lagertemp.

2-8°C

SMILES String

ClC(Cl)=S

InChI

1S/CCl2S/c2-1(3)4

InChIKey

ZWZVWGITAAIFPS-UHFFFAOYSA-N

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Anwendung

Reagent used to prepare a bulky thiourea ligand for palladium-catalyzed aerobic oxidation of alcohols to aldehydes and ketones.

Piktogramme

Skull and crossbonesCorrosion
GHS06,GHS05

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3

Zielorgane

Respiratory system

Lagerklassenschlüssel

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 1

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Analysenzertifikate (COA)

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T A Lewis et al.
Journal of bacteriology, 177(8), 2204-2208 (1995-04-01)
Pseudomonas sp. strain KC transforms carbon tetrachloride into carbon dioxide and nonvolatile products, without chloroform as an intermediate. To define the pathway for hydrolysis, nonvolatile products were analyzed. Condensation products containing the carbon atom of carbon tetrachloride as carbonyl and
Cheng Li et al.
Colloids and surfaces. B, Biointerfaces, 171, 159-166 (2018-07-22)
Dual mode imaging technology is widely developed to achieve the early-stage precision cancer diagnosis. Here we designed a dual-modal magnetic resonance/near infrared fluorescence optical imaging contrast agent (GdF-SS-NIR783) with the fluorescence activatable and safer gadofullerene. The nanoprobes were fabricated by
Christof Jung et al.
The journal of physical chemistry. A, 110(16), 5317-5325 (2006-04-21)
The dispersed fluorescence spectrum of the ground electronic state of thiophosgene, SCCl2, is analyzed in a very complex region of vibrational excitation, 7000-9000 cm(-1). The final result is that most of the inferred excited vibrational levels are assigned in terms
W Kedzierski et al.
The Journal of chemical physics, 120(19), 9087-9089 (2004-07-23)
A special xenon matrix detector has been used to study the production of S(1S) following controlled electron impact on thiophosgene (Cl2CS) targets over an electron energy range from threshold to 400 eV. Time-of-flight spectroscopy has been used to measure S(1S)
Youlia Hagooly et al.
The Journal of organic chemistry, 73(17), 6780-6783 (2008-08-13)
A general preparation for aromatic and aliphatic, cyclic as well as linear, symmetric and asymmetric difluoromethylenedioxy derivatives is described. The alcohols were reacted with thiophosgene to give thiocarbonates, which in turn were reacted with BrF3. The fluorination step is complete
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