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D7137

Sigma-Aldrich

Dihydroxyacetone phosphate dilithium salt

≥93% dry basis (enzymatic)

Sinônimo(s):

1,3-Dihydroxy-2-propanone 1-phosphate dilithium salt, 1-Hydroxy-3-(phosphonooxy)-2-propanone dilithium salt, DHAP

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About This Item

Fórmula empírica (Notação de Hill):
C3H5Li2O6P
Número CAS:
102783-56-2
Peso molecular:
181.92
Beilstein:
1708891
Número MDL:
MFCD00077731
Código UNSPSC:
12352201
ID de substância PubChem:
24894082
NACRES:
NA.25
Preço e disponibilidade não estão disponíveis no momento.

fonte biológica

bovine (casein)

Nível de qualidade

200

Ensaio

≥93% dry basis (enzymatic)

Formulário

powder

Impurezas

~0.2 mol % D-glyceraldehyde 3-phosphate

cor

white

solubilidade

soluble 50mg plus 1ml of H2O, clear, colorless to faintly yellow

traços de ânion

phosphate (PO43-): ~5 mol %

traços de cátion

Li: 5.5-8.0% (dry basis)

temperatura de armazenamento

−20°C

cadeia de caracteres SMILES

[Li+].[Li+].OCC(=O)COP([O-])([O-])=O

InChI

1S/C3H7O6P.2Li/c4-1-3(5)2-9-10(6,7)8;;/h4H,1-2H2,(H2,6,7,8);;/q;2*+1/p-2

chave InChI

QWIKESRFRWLYIA-UHFFFAOYSA-L

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Aplicação

Dihydroxyacetone phosphate (DHAP) is used in fructose metabolism, triose and glycation research. It is used in studies involving the metabolism of three-carbon sugar pools and their roles in physiological and physical processes.[1] DHAP may be used as a substrate to help identify, differentiate and characterize fructose-bisphosphate aldolase(s) (ALDOA) and triosephosphate isomerase(s).[2] DHAP may be used to study cellular glycation stress.[3]

Ações bioquímicas/fisiológicas

A metabolic intermediate involved in many pathways, including glycolysis and the Calvin cycle.
Dihydroxyacetone phosphate (DHAP) is a metabolic intermediate involved in many pathways, including glycolysis, gluconeogenesis, glycerol metabolism, phosphatidic acid synthesis, fat metabolism, and the Calvin cycle.

Atenção

Unlike the dimethyl ketal, does not require hydrolysis prior to use as a substrate.

Nota de preparo

Enzymatically prepared.

Outras notas

To gain a comprehensive understanding of our extensive range of Monosaccharides for your research, we encourage you to visit our Carbohydrates Category page.

Código de classe de armazenamento

11 - Combustible Solids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Equipamento de proteção individual

Eyeshields, Gloves, type N95 (US)

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Certificados de análise (COA)

Lot/Batch Number
0000379265
0000379265
0000348217
0000348215
0000348214

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Xi Luo et al.
Scientific reports, 7(1), 15170-15170 (2017-11-11)
Matrix-assisted laser desorption/ionization (MALDI) mass spectrometry has been widely used for biomolecular analysis. However, with conventional MALDI, it is difficult to analyse low-molecular-weight compounds because of the interference of matrix ion signals. Here, we report a matrix-free on-chip pulse-heating desorption/ionization
Chiara Fania et al.
PloS one, 12(6), e0179280-e0179280 (2017-06-20)
In the diagnosis of Alzheimer's disease (AD) total tau (T-tau), tau phosphorylated at threonine 181 (P-tau181), and the 42 amino acid isoform of alpha β-amyloid (Aβ) are well established surrogate CSF markers. However, there is a constant need for new
Daisuke Takagi et al.
Plant & cell physiology, 55(2), 333-340 (2014-01-11)
Sugar-derived reactive carbonyls (RCs), including methylglyoxal (MG), are aggressive by-products of oxidative stress known to impair the functions of multiple proteins. These advanced glycation end-products accumulate in patients with diabetes mellitus and cause major complications, including arteriosclerosis and cardiac insufficiency.
Saheem Ahmad et al.
PloS one, 8(9), e72128-e72128 (2013-09-12)
Non-enzymatic glycation is the addition of free carbonyl group of reducing sugar to the free amino groups of proteins, resulting in the formation of a Schiff base and an Amadori product. Dihydroxyacetone (DHA) is one of the carbonyl species which
Sebastien Elis et al.
Journal of ovarian research, 10(1), 74-74 (2017-11-11)
Supplementation of bovine oocyte-cumulus complexes during in vitro maturation (IVM) with 1 μM of docosahexaenoic acid (DHA), C22:6 n-3 polyunsaturated fatty acid, was reported to improve in vitro embryo development. The objective of this paper was to decipher the mechanisms of
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