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209619

Sigma-Aldrich

Potassium carbonate

ACS reagent, ≥99.0%

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About This Item

Fórmula linear:
K2CO3
Número CAS:
Peso molecular:
138.21
Beilstein:
4267587
Número CE:
Número MDL:
Código UNSPSC:
12352302
ID de substância PubChem:
NACRES:
NA.21

grau

ACS reagent

Nível de qualidade

Ensaio

≥99.0%

forma

powder or crystals

Impurezas

≤0.004% S compounds as (SO42-)
≤0.005% silica
≤0.01% insolubles

pH

11-13 (25 °C, 138 g/L)

pf

891 °C (lit.)

traços de ânion

chloride (Cl-): ≤0.003%
phosphate (PO43-): ≤0.001%

traços de cátion

Ca: ≤0.005%
Fe: ≤5 ppm
Mg: ≤0.002%
Na: ≤0.02%
heavy metals: ≤5 ppm (by ICP-OES)

cadeia de caracteres SMILES

[K+].[K+].[O-]C([O-])=O

InChI

1S/CH2O3.2K/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2

chave InChI

BWHMMNNQKKPAPP-UHFFFAOYSA-L

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Descrição geral

Potassium carbonate is an inorganic base. It participates as a base in the palladacycle catalyzed Heck reaction of chlorobenzene with styrene. Addition of amino acids (glycine, sarcosine and proline) to K2CO3 (solvent) promotes the absorption of CO2.

Aplicação

Potassium carbonate has been used in the preparation of disulfonated bis[4-(3-aminophenoxy)phenyl]sulfone, a disulfonated diamine monomer.
It may be used in the following studies:
  • As a reagent in the synthesis of polysubstituted iodobenzene derivatives.
  • As a base for the synthesis of high molecular weight homopolymers and copolymers derived from various bisphenols.
  • As a base for the Suzuki coupling of aryl halides with aryl boronic acids.
  • The Heck reaction of styrene and bromobenzene.

Informações legais

Redi-Dri is a trademark of Sigma-Aldrich Co. LLC

Pictogramas

Exclamation mark

Palavra indicadora

Warning

Frases de perigo

Classificações de perigo

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Órgãos-alvo

Respiratory system

Código de classe de armazenamento

13 - Non Combustible Solids

Classe de risco de água (WGK)

WGK 1

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable


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A kinetic study of CO2 capture with potassium carbonate solutions promoted with various amino acids: glycine, sarcosine and proline.
Thee H, et al.
International Journal of Greenhouse Gas Control, 20, 212-222 (2014)
Robert Möckel et al.
Organic letters, 17(7), 1644-1647 (2015-03-21)
The cobalt-catalyzed Diels-Alder reaction of trimethylsilyl-substituted alkynes with 1,3-dienes led to dihydroaromatic intermediates which were transformed into iodobenzene derivatives. For this transformation, the dihydroaromatic intermediates had to be oxidized and the trimethylsilyl-substituted arene had to undergo a silicon-iodine exchange reaction.
Chelating N-heterocyclic carbene ligands in palladium-catalyzed Heck-type reactions.
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Journal of Organometallic Chemistry, 557(1), 93-96 (1998)
Synthesis, kinetic observations and characteristics of polyarylene ether sulphones prepared via a potassium carbonate DMAC process.
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Polymer, 25(12), 1827-1836 (1984)
Heck reaction using palladium complexed to dendrimers on silica.
Alper H, et al.
Canadian Journal of Chemistry, 78(6), 920-924 (2000)

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