The Journal of organic chemistry, 69(6), 2191-2193 (2004-04-03)
A total synthesis following the sequence in Scheme 1 confirms that porritoxin possesses revised structure 3, not the originally assigned 1. A key reaction was the use of iron pentacarbonyl to formylate an aryllithium when DMF and methyl formate proved
The Journal of chemical physics, 135(2), 024301-024301 (2011-07-20)
A potential energy surface for helium interacting with methyl formate has been computed using high-level electronic structure methods. The interaction energies obtained on a three-dimensional grid have been fitted by an analytic function of interatomic distances with correct asymptotic behavior
Archives of toxicology, 86(2), 285-292 (2011-10-05)
Methyl formate (MF) is a volatile solvent with several industrial applications. The acute airway effects of MF were evaluated in a mouse bioassay, allowing the assessment of sensory irritation of the upper airways, airflow limitation of the conducting airways and
European journal of oral sciences, 108(4), 335-340 (2000-08-18)
Methylene chloride is used as softening agent for guttapercha and as adhesion promotor for polymethylmethacrylate (PMMA). However, methylene chloride has been found to be carcinogenic. It was the aim of the present work to search for harmless substitutes for methylene
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