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550256

Sigma-Aldrich

Silver methanesulfonate

Sinônimo(s):

Silver methylsulfonate, Methanesulfonic acid silver salt

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About This Item

Fórmula linear:
AgSO3CH3
Número CAS:
2386-52-9
Peso molecular:
202.97
Número CE:
219-199-2
Número MDL:
MFCD00064795
Código UNSPSC:
12161600
ID de substância PubChem:
24879101
NACRES:
NA.22

forma

solid

adequação da reação

core: silver
reagent type: catalyst

pf

252-256 °C (lit.)

cadeia de caracteres SMILES

[Ag+].CS([O-])(=O)=O

InChI

1S/CH4O3S.Ag/c1-5(2,3)4;/h1H3,(H,2,3,4);/q;+1/p-1

chave InChI

MLKQJVFHEUORBO-UHFFFAOYSA-M

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Aplicação

Gold Catalysts — 21st Century ′Gold Rush′
Catalyst for:
  • Heterocyclization reactions
  • CO2-mediated rearrangement of propargyl alcohols for the synthesis of a,ß-unsaturated ketones and esters

Pictogramas

Exclamation mark
GHS07

Palavra indicadora

Warning

Frases de perigo

H315,H319,H335

Classificações de perigo

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Órgãos-alvo

Respiratory system

Código de classe de armazenamento

11 - Combustible Solids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Equipamento de proteção individual

dust mask type N95 (US), Eyeshields, Gloves

Certificados de análise (COA)

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Tsung-Ming Shih et al.
Chemico-biological interactions, 187(1-3), 207-214 (2010-03-13)
This study compared the ability of nine oximes (HI-6, HLö7, MMB-4, TMB-4, carboxime, ICD585, ICD692, ICD3805, and 2-PAM) to reactivate in vivo cholinesterase (ChE) in blood, brain, and peripheral tissues in guinea pigs intoxicated by one of four organophosphorus nerve
Wenyuan Liu et al.
Journal of pharmaceutical and biomedical analysis, 52(4), 603-608 (2010-02-09)
10-O-(N,N-dimethylaminoethyl)-ginkgolide B methanesulfonate (XQ-1H), a novel active derivative of ginkgolide B, is a platelet-activating factor antagonist which is being under clinical trial. Two unknown related impurities were observed in analysis of XQ-1H bulk drug. A scaling up preparative liquid chromatography
Renata Solarska et al.
Nanoscale, 4(5), 1553-1556 (2012-02-01)
Nanostructuring of semiconductor films offers the potential means for producing photoelectrodes with improved minority charge carrier collection. Crucial to the effective operation of the photoelectrode is also the choice of a suitable electrolyte. The behaviour of the nanostructured WO(3) photoanodes
Cassandra J Gaston et al.
Environmental science & technology, 44(5), 1566-1572 (2010-02-04)
Dimethyl sulfide (DMS), produced by oceanic phytoplankton, is oxidized to form methanesulfonic acid (MSA) and sulfate, which influence particle chemistry and hygroscopicity. Unlike sulfate, MSA has no known anthropogenic source making it a useful tracer for ocean-derived biogenic sulfur. Despite
Neal W Sach et al.
Organic letters, 14(15), 3886-3889 (2012-07-18)
A general synthesis of aryl ethers from primary and secondary alcohols and aryl mesylates is presented. The reaction proceeds via a sulfonyl-transfer mechanism. In this paper, we compare the sulfonyl transfer reaction to Mitsunobu ether formation. The reaction can be
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