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393436

Sigma-Aldrich

Tris(2,6-dimethoxyphenyl)phosphine

98%

Sinônimo(s):

DMPP

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About This Item

Fórmula linear:
[(CH3O)2C6H3]3P
Número CAS:
85417-41-0
Peso molecular:
442.44
Número MDL:
MFCD00192558
Código UNSPSC:
12352112
ID de substância PubChem:
24864518

Ensaio

98%

Formulário

powder

adequação da reação

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
reaction type: Cross Couplings

pf

145-147 °C (lit.)

grupo funcional

phosphine

cadeia de caracteres SMILES

COc1cccc(OC)c1P(c2c(OC)cccc2OC)c3c(OC)cccc3OC

InChI

1S/C24H27O6P/c1-25-16-10-7-11-17(26-2)22(16)31(23-18(27-3)12-8-13-19(23)28-4)24-20(29-5)14-9-15-21(24)30-6/h7-15H,1-6H3

chave InChI

CMLWFCUAXGSMBB-UHFFFAOYSA-N

Aplicação

Catalyst for:
  • Preparation of chiral building blocks via hydroalkynylation reactions or ynolates
  • Three-component aza-Morita-Baylis-Hillman reactions (aza-MBH)
  • Atom-economic synthesis of nitrogen heterocycles and ynenoates from alkynes
  • Oxycylizations of allendiols
  • Enantioselective aldol reactions
  • Pd-mediated cross-coupling, Pd- and Cu-mediated benzannulation reactions and copper-mediated dimerization reactions

Pictogramas

Exclamation mark
GHS07

Palavra indicadora

Warning

Frases de perigo

H315,H319,H335

Classificações de perigo

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Órgãos-alvo

Respiratory system

Código de classe de armazenamento

11 - Combustible Solids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Equipamento de proteção individual

dust mask type N95 (US), Eyeshields, Gloves

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Certificados de análise (COA)

Lot/Batch Number
SHBC3197V
02819TH
11528DZ
07321TO
03804TN

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