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379212

Sigma-Aldrich

Hexamethyldisilazane

ReagentPlus®, 99.9%

Sinônimo(s):

1,1,1,3,3,3-Hexamethyldisilazane, HMDS

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About This Item

Fórmula linear:
(CH3)3SiNHSi(CH3)3
Número CAS:
999-97-3
Peso molecular:
161.39
Beilstein:
635752
Número CE:
213-668-5
Número MDL:
MFCD00008259
Código UNSPSC:
12352103
ID de substância PubChem:
24863226
NACRES:
NA.23

Nível de qualidade

200

linha de produto

ReagentPlus®

Ensaio

99.9%

Formulário

liquid

índice de refração

n20/D 1.407 (lit.)

p.e.

125 °C (lit.)

cadeia de caracteres SMILES

C[Si](C)(C)N[Si](C)(C)C

InChI

1S/C6H19NSi2/c1-8(2,3)7-9(4,5)6/h7H,1-6H3

chave InChI

FFUAGWLWBBFQJT-UHFFFAOYSA-N

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Descrição geral

Hexamethyldisilazane (HDMS) is an organoslicon compound. HDMS is a colorless liquid used as a reagent and precursor in organic synthesis and organometallic chemistry. It is also used as a sol-gel precursor to fabricate thin films for semiconductor devices.

Aplicação

Hexamethyldisilazane can be used:
  • As a precursor to fabricate multilayer quantum dot light-emitting diodes.
  • To modify dielectric surfaces of organic thin film transistors.
  • To fabricate superhydrophobic coatings on epoxy resins.
  • For the silylation of alcohols and phenols.

Informações legais

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictogramas

FlameSkull and crossbones
GHS02,GHS06

Palavra indicadora

Danger

Classificações de perigo

Acute Tox. 3 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Flam. Liq. 2

Código de classe de armazenamento

3 - Flammable liquids

Classe de risco de água (WGK)

WGK 2

Ponto de fulgor (°F)

52.5 °F - closed cup

Ponto de fulgor (°C)

11.4 °C - closed cup

Equipamento de proteção individual

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Escolha uma das versões mais recentes:

Certificados de análise (COA)

Lot/Batch Number
SHBM6136
SHBJ6186
SHBH7587
SHBG6192V
SHBF8354V

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Se precisar de uma versão específica, você pode procurar um certificado específico pelo número do lote ou da remessa.

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Clorotrimetilsilano ≥98.0% (GC)

Sigma-Aldrich

92361

Clorotrimetilsilano

Osmium tetroxide solution suitable for electron microscopy, 4% in H2O

Sigma-Aldrich

75632

Osmium tetroxide solution

Clorotrimetilsilano derivatization grade (GC derivatization), LiChropur™, ≥99.0% (GC)

Supelco

89595

Clorotrimetilsilano

Hexamethyldisilazane-mediated full-solution-processed inverted quantum dot-light-emitting diodes
Yan Fu, et al.
Journal of Materials Chemistry, 5, 522-526 (2017)
Ar/HMDS Plasma Jet as a Tool for Superhydrophobic Coatings on Epoxy Resin
Jingang Wang, et al.
Nanotechnology, IEEE Transactions, 50, 1867-1874 (2022)
D F Bray et al.
Microscopy research and technique, 26(6), 489-495 (1993-12-15)
Three different drying methods, critical-point drying (CPD), Peldri II, and hexamethyldisilazane (HMDS), were compared using representative animal (rat kidney, trachea, duodenum, lung, and red blood cells) and plant (leaves from ten species of monocotyledons and dicotyledons) specimens. All three drying
High performance organic thin film transistors using chemically modified bottom contacts and dielectric surfaces
Organic Electronics, 15, 2073-2078 (2014)
G Chiavari et al.
Journal of chromatography. A, 922(1-2), 235-241 (2001-08-07)
Alpha-amino acids were pyrolysed at 600 degrees C in the presence of hexamethyldisilazane (HMDS) and the formed volatile products were analysed on line by gas chromatography-mass spectrometry (GC-MS). Glycine, alanine, valine, leucine, isoleucine, norleucine, methionine, phenylalanine yielded principally the trimethylsilyl
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