37275

(+)-Dihydrocarvone

mixture of isomers

• Sinônimo(s): (2R,5R)-5-Isopropenyl-2-methylcyclohexanone
• Fórmula empírica (Notação de Hill): C₁₀H₁₆O
• Número CAS: 5524-05-0
• Peso molecular: 152.23
• Beilstein: 2044615
• Número CE: 226-872-4
• Número MDL: MFCD00001636
• Código UNSPSC: 12352115
• ID de substância PubChem: 57649710
• NACRES: NA.22

Propriedades

• Formulário: liquid
• atividade óptica: [α]20/D +20±2°, neat
• composição: n-(+)-dihydrocarvone, ~77% ; iso-(+)-dihydrocarvone, ~20%
• índice de refração: n20/D 1.471
• densidade: 0.928 g/mL at 20 °C (lit.)
• grupo funcional: ketone
• cadeia de caracteres SMILES: CC1CCC(CC1=O)C(C)=C
• InChI: 1S/C10H16O/c1-7(2)9-5-4-8(3)10(11)6-9/h8-9H,1,4-6H2,2-3H3
• chave InChI: AZOCECCLWFDTAP-UHFFFAOYSA-N

Descrição

Descrição geral

(+)-Dihydrocarvone, a monoterpenoid compound[1] found in caraway oil,[2] is a key building block to synthesize sesquiterpenes.[3] It is generally produced either by the hydrogenation of carvone or oxidation of limonene.[2]

Aplicação

(+)-Dihydrocarvone may be used in the following processes:

• Synthesis of dispiro 1,2,4,5-tetraoxanes, which show potent anti-malarial activity.[4]
• Synthesis of an epoxylactone by oxidation, which can undergo copolymerization with ε-caprolactone to form cross-linked copolymers with shape memory properties.[2]
• Synthesis of α-Cyperone, a eudesmane type sesquiterpenoid compound with potent insecticidal activity.[5]

Informações de segurança

• Código de classe de armazenamento: 10 - Combustible liquids
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): 215.6 °F - closed cup
• Ponto de fulgor (°C): 102 °C - closed cup
• Equipamento de proteção individual: Eyeshields, Gloves