124931

(R)-(−)-Carvone

98%

• Sinônimo(s): (−)-Carvone, (R)-5-Isopropenyl-2-methyl-2-cyclohexenone, p-Mentha-6,8-dien-2-one, Carvol
• Fórmula empírica (Notação de Hill): C₁₀H₁₄O
• Número CAS: 6485-40-1
• Peso molecular: 150.22
• Beilstein: 2206714
• Número CE: 229-352-5
• Número MDL: MFCD00001578
• Código UNSPSC: 12352115
• ID de substância PubChem: 24847635
• NACRES: NA.22

Propriedades

• densidade de vapor: 5.2 (vs air)
• pressão de vapor: 0.4 mmHg ( 20 °C)
• Ensaio: 98%
• forma: liquid
• atividade óptica: [α]20/D −61°, neat
• índice de refração: n20/D 1.497 (lit.)
• pb: 227-230 °C (lit.)
• densidade: 0.959 g/mL at 25 °C (lit.)
• cadeia de caracteres SMILES: CC(=C)[C@@H]1CC=C(C)C(=O)C1
• InChI: 1S/C10H14O/c1-7(2)9-5-4-8(3)10(11)6-9/h4,9H,1,5-6H2,2-3H3/t9-/m1/s1
• chave InChI: ULDHMXUKGWMISQ-SECBINFHSA-N

Descrição

Descrição geral

(R)-(−)-Carvone is a monoterpenoid. Its ozonolysis in the gaseous phase has been proposed. Aldehydes (formaldehyde) and biradicals were obtained as the major products. It participates in the diastereoselective synthesis of homochiral octalones.

Aplicação

(R)-(−)-Carvone may be employed as starting reagent for the synthesis of enantiopure (R)-(+)-3-methyl-6-isopropenyl-cyclohept-3-enone-1, a useful intermediate formed during the synthesis of terpenoids. It may be employed as starting reagent for the synthesis of differently protected (4S,6R,7R)-trihydroxy-1-octyne derivatives.

Chiral starting material.

Informações de segurança

• Pictogramas: GHS07
• Palavra indicadora: Warning
• Frases de perigo: H302,H317
• Declarações de precaução: P261 - P264 - P272 - P280 - P301 + P312 - P302 + P352
• Classificações de perigo: Acute Tox. 4 Oral - Skin Sens. 1
• Código de classe de armazenamento: 10 - Combustible liquids
• Classe de risco de água (WGK): WGK 1
• Ponto de fulgor (°F): 192.2 °F - closed cup
• Ponto de fulgor (°C): 89 °C - closed cup
• Equipamento de proteção individual: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter