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Manganese(II) chloride

Manganese(II) chloride
1 of 1 reviewers received a sample product or took part in a promotion

beads, 98%

Sinônimo(s):

Manganese dichloride, Sacchite

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25 G
R$ 411,00
500 G
R$ 495,00
2 KG
R$ 1.091,00

R$ 411,00

Disponível para enviar em22 de abril de 2025Detalhes

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25 G
R$ 411,00
500 G
R$ 495,00
2 KG
R$ 1.091,00

About This Item

Fórmula linear:
MnCl2
Número CAS:
7773-01-5
Peso molecular:
125.84
Número MDL:
MFCD00011114
Código UNSPSC:
12161600
ID de substância PubChem:
24859717
NACRES:
NA.22

R$ 411,00

Disponível para enviar em22 de abril de 2025Detalhes

Solicite uma grande encomenda

Nível de qualidade

100

Ensaio

98%

Formulário

beads

adequação da reação

core: manganese
reagent type: catalyst

pf

652 °C (lit.)

densidade

2.98 g/mL at 25 °C (lit.)

cadeia de caracteres SMILES

Cl[Mn]Cl

InChI

1S/2ClH.Mn/h2*1H;/q;;+2/p-2

chave InChI

GLFNIEUTAYBVOC-UHFFFAOYSA-L

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Categorias relacionadas

Aplicação

A novel high-spin hexanuclear Mn(III) cluster, [NaMn6(OMe)12(dbm)6]+, was synthesized via MnCl2 oxidation with simultaneous NaOMe promoted aggregation. This cluster has an unprecedented cyclic structure and 24 unpaired electrons in its ground state.[1] Also used in the formation of an active Mn(0) speciesuseful for radical cyclization reactions.[2]
Starting material for preparation of organomanganese chloride reagents; catalyst for reduction of vinyl and aryl halides, stereoselective coupling of vinyl iodides, and alkylation of enol triflates; also used for Mn-Cu-catalyzed conjugate addition of RMgX to enones and for Mn-catalyzed acylation of RMgX by acyl chlorides; in combination with NaBH4 is diastereoselective reducing agent; starting material for the preparation of Mn enolates regio- and stereo-selectively.

Palavra indicadora

Danger

Frases de perigo

H301,H318,H373

Classificações de perigo

Acute Tox. 3 Oral - Eye Dam. 1 - STOT RE 2

Órgãos-alvo

Brain

Código de classe de armazenamento

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

Classe de risco de água (WGK)

WGK 2

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Equipamento de proteção individual

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

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Certificados de análise (COA)

Lot/Batch Number
MKCF5125
MKBG2452V
01326HT
09706ED
09806ED

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Abbati, G.L. et al.
Inorganic Chemistry, 37, 1430-1430 (1998)
Tang, J. et al.
Tetrahedron, 55, 1893-1893 (1999)
Tora Sund Morken et al.
Pediatric research, 73(2), 171-179 (2012-11-24)
Hypoxia-ischemia (HI) induces delayed inflammation and long-term gray and white matter brain injury that may be altered by hyperoxia. HI and 2 h of hyperoxia (100% O2) or room air (21% O2) in 7-d-old (P7) rats were studied by magnetic resonance
Oliviero L Gobbo et al.
Contrast media & molecular imaging, 7(6), 542-546 (2012-09-20)
Lung parenchyma remains one of the most difficult tissues to be imaged by means of magnetic resonance imaging (MRI). Several MRI techniques are routinely used for lung imaging. However, manganese-enhancement MRI (MEMRI) technique has not been associated with pulmonary MRI.
M R Sepúlveda et al.
Contrast media & molecular imaging, 7(4), 426-434 (2012-06-01)
Manganese is a vital element and cofactor of many key enzymes, but it is toxic at high levels, causing pronounced disturbances in the mammalian brain. Magnetic resonance imaging (MRI) studies using manganese ions as a paramagnetic contrast agent are often
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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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