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29580

Sigma-Aldrich

cis,cis-1,5-Cyclooctadiene

≥98.0% (GC)

Sinônimo(s):

COD

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About This Item

Fórmula empírica (Notação de Hill):
C8H12
Número CAS:
1552-12-1
Peso molecular:
108.18
Beilstein:
1209288
Número CE:
216-291-4
Número MDL:
MFCD00001752
Código UNSPSC:
12352100
ID de substância PubChem:
57648379

Ensaio

≥98.0% (GC)

índice de refração

n20/D 1.493

solubilidade

water: soluble 0.05 g/L

densidade

0.880 g/mL at 20 °C (lit.)

cadeia de caracteres SMILES

C1CC=CCCC=C1

InChI

1S/C8H12/c1-2-4-6-8-7-5-3-1/h1-2,7-8H,3-6H2/b2-1-,8-7-

chave InChI

VYXHVRARDIDEHS-QGTKBVGQSA-N

Descrição geral

Surface grafting of cis,cis-1,5-cyclooctadiene (cyclic olefin) with low strain energy was explored using ring-opening metathesis polymerization in the vapor phase. The inclusion complex of cis,cis-1,5-cyclooctadiene with β-cyclodextrin (β-CD) was studied by using proton NMR spectroscopy.

Aplicação

cis,cis-1,5-Cyclooctadiene (COD) has been employed as ligand:
  • during regio- and stereoselective synthesis of (Z)-1,2-dihaloalkenes
  • in the preparation of metal complexes, e.g. bis-COD-nickel, a versatile reagent for preparing (PI)-allylnickel halides

Palavra indicadora

Danger

Classificações de perigo

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Asp. Tox. 1 - Flam. Liq. 3

Código de classe de armazenamento

3 - Flammable liquids

Classe de risco de água (WGK)

WGK 2

Ponto de fulgor (°F)

89.6 °F - closed cup

Ponto de fulgor (°C)

32 °C - closed cup

Equipamento de proteção individual

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificados de análise (COA)

Lot/Batch Number
BCBL2155V
1369462V
1369462
429961/1
368430/1

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Maria Felisa Z Lerum et al.
Langmuir : the ACS journal of surfaces and colloids, 27(9), 5403-5409 (2011-04-08)
Surface grafting of cyclic olefins with low strain energies, including cyclopentene (CP), 1,4-cyclohexadiene (CHD), cycloheptene (CHP), cis-cyclooctene (CO), cis,cis-1,5-cyclooctadiene (COD), 1,3,5,7-cyclooctatetraene (COT), cyclododecene (CD), and trans,trans,cis-1,5,9-cyclododecatriene (CDT), was explored using ring-opening metathesis polymerization in the vapor phase. These monomers do
Cao Yujuan et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 73(4), 713-718 (2009-04-22)
The inclusion behavior of cis-cyclooctene, cis, cis-1, 3-cyclooctadiene and cis, cis-1, 5-cyclooctadiene with beta-cyclodextrin (beta-CD) was studied by using (1)H NMR method in D(2)O/CD(3)OD solution and PM3 quantum-chemical simulation in vacuum. The experimental results indicate that each guest molecule penetrates
Jhane Rose P Encarguez et al.
Environmental monitoring and assessment, 191(9), 532-532 (2019-08-04)
Macajalar Bay in the southern Philippines has become an attractive thoroughfare with recent developments, rendering anthropogenic input to the coastal waters. Expediting coastal resource management strategies necessitates the present study on coastal water characteristics. This was aided with distribution pattern
Ting Ma et al.
Science advances, 6(1), eaau3798-eaau3798 (2020-01-11)
Increased human activity threatens inland water quality in China. Major efforts have been made to alleviate water pollution since 2001. Understanding how water quality responds to these forces can help to guide future efforts to maintain water security and sustainability.
Qilin Wang et al.
Environmental science & technology, 51(17), 9800-9807 (2017-08-05)
Biological nitrogen removal through the nitrite pathway (NH
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