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Documentos

295485

Sigma-Aldrich

Bromomethane

≥99%

Sinônimo(s):

Methyl bromide

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About This Item

Fórmula empírica (Notação de Hill):
CH3Br
Número CAS:
Peso molecular:
94.94
Beilstein:
1209223
Número CE:
Número MDL:
Código UNSPSC:
12352100
ID de substância PubChem:
NACRES:
NA.22

densidade de vapor

3.3 (20 °C, vs air)

Nível de qualidade

pressão de vapor

1420 mmHg ( 20 °C)

Ensaio

≥99%

temperatura de autoignição

996 °F

Lim. expl.

~16 %

pb

4 °C (lit.)

pf

−94 °C (lit.)

solubilidade

water: soluble

densidade

3.3 g/mL at 25 °C (lit.)

cadeia de caracteres SMILES

CBr

InChI

1S/CH3Br/c1-2/h1H3

chave InChI

GZUXJHMPEANEGY-UHFFFAOYSA-N

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Descrição geral

Bromomethane (methyl bromide) is the most effective soil fumigant for killing plant pests, its use is being phased out because its emissions from soil can lead to stratospheric ozone depletion. The bimolecular nucleophilic substitution (S(N)2) reaction of methyl bromide and OH- in aqueous solution has been investigated using a multilayered-representation quantum mechanical and molecular mechanics methodology.

Aplicação

Please view www.aldrich.com/epaods regarding the EPA′s request for application information of Ozone Depleting Substances

Produtos recomendados

Brass control valve Z146943 or either of brass regulators Z146706 and Z146714 is recommended.

recomendado

regulador

Palavra indicadora

Danger

Classificações de perigo

Acute Tox. 2 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 2 - Eye Irrit. 2 - Muta. 2 - Ozone 1 - Press. Gas Liquefied gas - Skin Irrit. 2 - STOT RE 2 - STOT SE 3

Órgãos-alvo

Central nervous system, Respiratory system

Código de classe de armazenamento

2A - Gases

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

<-22.0 °F - liquid

Ponto de fulgor (°C)

< -30 °C - liquid

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves


Certificados de análise (COA)

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Richeng Xuan et al.
Environmental science & technology, 44(23), 9080-9085 (2010-11-10)
Despite generally being considered the most effective soil fumigant, methyl bromide (MeBr) use is being phased out because its emissions from soil can lead to stratospheric ozone depletion. However, a large amount is still currently used due to Critical Use
Guy J Hallman et al.
Journal of economic entomology, 104(1), 63-68 (2011-03-17)
Methyl bromide fumigation is widely used as a phytosanitary treatment. Mexican fruit fly, Anastrepha ludens (Loew) (Diptera: Tephritidae), is a quarantine pest of several fruit, including citrus (Citrus spp.), exported from Texas, Mexico, and Central America. Recently, live larvae have
Kathryn Hughes Barry et al.
Cancer causes & control : CCC, 23(6), 807-818 (2012-04-25)
Methyl bromide is a genotoxic soil fumigant with high acute toxicity, but unknown human carcinogenicity. Although many countries have reduced methyl bromide use because of its ozone depleting properties, some uses remain in the United States and other countries, warranting
Yulong Xu et al.
The Journal of chemical physics, 137(18), 184501-184501 (2012-11-21)
The bimolecular nucleophilic substitution (S(N)2) reaction of CH(3)Br and OH(-) in aqueous solution was investigated using a multilayered-representation quantum mechanical and molecular mechanics methodology. Reactant complex, transition state, and product complex are identified and characterized in aqueous solution. The potentials
Lygia T Budnik et al.
Environmental health : a global access science source, 11, 5-5 (2012-01-31)
Although ozone-depleting methyl bromide was destined for phase-out by 2005, it is still widely applied as a consequence of various critical-use-exemptions and mandatory international regulations aiming to restrict the spread of pests and alien species (e.g. in globalized transport and

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